Hostname: page-component-586b7cd67f-l7hp2 Total loading time: 0 Render date: 2024-11-25T15:35:20.765Z Has data issue: false hasContentIssue false

Multifunctional Nanocomposite Coatings

Published online by Cambridge University Press:  01 February 2011

Corné H.A. Rentrop
Affiliation:
TNO-TPD Materials research & technology, P.O. box 595, 5600 AN Eindhoven, The Netherlands
Lawrence F. Batenburg
Affiliation:
TNO-TPD Materials research & technology, P.O. box 595, 5600 AN Eindhoven, The Netherlands
Roelant A. Van Dam
Affiliation:
TNO-TPD Materials research & technology, P.O. box 595, 5600 AN Eindhoven, The Netherlands
Marinus P. Hogerheide
Affiliation:
TNO-TPD Materials research & technology, P.O. box 595, 5600 AN Eindhoven, The Netherlands
Harry A. Meinema
Affiliation:
TNO-TPD Materials research & technology, P.O. box 595, 5600 AN Eindhoven, The Netherlands
Leon H. Gielgens
Affiliation:
TNO-TPD Materials research & technology, P.O. box 595, 5600 AN Eindhoven, The Netherlands
Hartmut R. Fischer*
Affiliation:
TNO-TPD Materials research & technology, P.O. box 595, 5600 AN Eindhoven, The Netherlands
*
* To whom correspondence should be addressed
Get access

Abstract

Multifunctional nanocomposite coatings and bulk materials have been developed on the basis of a combination of purely organic, as well as hybrid organic-inorganic polymeric matrices and anisotropic synthetic and natural clays. The clays have been chemically modified in such a way that they became compatible to the polymeric matrices. Clay platelets may be separated by modification with an organic molecule that contains two or more charged functional groups. The cations or anions located between the clay sheets are exchanged with one of these organic functional groups, which results in the formation of clay platelets “coated” with charges, thereby causing a molecular dispersion. Depending on the nature of the organic molecule colored or colorless coatings and polymeric bulk materials, containing homogeneously dispersed separated clay platelets, have been obtained.

While retaining the basic functional properties of the materials new and/or improved properties have been introduced. This concerns in particular improved barrier properties, such as a decreased permeability for oxygen and water, improved corrosion resistance and increased thermal stability.

The composition of the wet coating systems is such that they can be properly applied and thermally or photo-chemically cured on various substrates such as glass, steel, aluminum and plastics. The bulk materials can be processed into final product shapes by conventional polymer processing techniques.

Type
Research Article
Copyright
Copyright © Materials Research Society 2000

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1 Smock, D., Modern Plastics International, 28, 28 (1998)Google Scholar
2 EP 0791 556, Nippon Paint Co., Ltd. (1997)Google Scholar
3 Kuchta, F.D., Lemstra, P.J., Keller, A., Batenburg, L.F., Fischer, H.R., MRS Symposium Series, 576, 363 (2000)Google Scholar
4 Kojima, Y., Usuki, A., Kawasumi, M., Okada, A. Fukushima, Kurauchi, Y, Kamigaito, T., O., , J. Mater. Res., 8, 11851189 (1993)Google Scholar
5 Usuki, A., Kato, M., Okada, A., Kurauchi, T., J. Appl. Polym. Sci. 63 137139 (1997)Google Scholar
6 Lee, J., Giannelis, E. Polymer preprints 38, 688689 (1997)Google Scholar
7 Fischer, H., Gielgens, L., Koster, T., Acta Polymerica, 50, 122 (1999)Google Scholar
8 Giannelis, E.P., Adv. Mater. 8, 29 (1996)Google Scholar
9 Patent pending NL-A-1013373, TNO, (1999)Google Scholar
10 Meinema, H., Rentrop, C., Breur, R., Ferrari, G., Thin Solid Films, 347, 16 (1999)Google Scholar
11 Usuki, A., Kojima, Y., Kawasumi, M., Okada, A., Fukushima, Y., Kurauchi, T., Kamigaito, O., J. Mater. Res. 5, 1179 (1993)Google Scholar