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Monocrystalline InP Nanotubes

Published online by Cambridge University Press:  01 February 2011

Erik. P. A. M. Bakkers
Affiliation:
Philips Research Laboratories, Prof. Holstlaan 4, 5656 AA Eindhoven, The Netherlands, Department of Nanoscience, Delft University of Technology, P.O. Box 5046, 2000 GA Delft, The Netherlands
Louis F. Feiner
Affiliation:
Philips Research Laboratories, Prof. Holstlaan 4, 5656 AA Eindhoven, The Netherlands, Department of Nanoscience, Delft University of Technology, P.O. Box 5046, 2000 GA Delft, The Netherlands
Marcel. A. Verheijen
Affiliation:
Philips Research Laboratories, Prof. Holstlaan 4, 5656 AA Eindhoven, The Netherlands, Department of Nanoscience, Delft University of Technology, P.O. Box 5046, 2000 GA Delft, The Netherlands
Jorden A. van Dam
Affiliation:
Philips Research Laboratories, Prof. Holstlaan 4, 5656 AA Eindhoven, The Netherlands, Department of Nanoscience, Delft University of Technology, P.O. Box 5046, 2000 GA Delft, The Netherlands
Silvano De Franceschi
Affiliation:
Philips Research Laboratories, Prof. Holstlaan 4, 5656 AA Eindhoven, The Netherlands, Department of Nanoscience, Delft University of Technology, P.O. Box 5046, 2000 GA Delft, The Netherlands
Leo Kouwenhoven
Affiliation:
Philips Research Laboratories, Prof. Holstlaan 4, 5656 AA Eindhoven, The Netherlands, Department of Nanoscience, Delft University of Technology, P.O. Box 5046, 2000 GA Delft, The Netherlands
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Abstract

Indium phosphide (InP) nanowires and nanotubes have been synthesized via the vapor-liquid-solid (VLS) growth mechanism. The wires as well as the tubes are crystalline and have the (bulk) zinc blende structure. Compared to the nanowires the nantubes are formed at higher temperatures. A simple model for the formation of the nanotubes is presented. The diameter of the wires and the wall thickness of the tubes can be controlled by the synthesis temperature. Photoluminescence measurements on individual wires show a strong polarization dependency. Moreover, the nanostructures exhibit a considerable blue shift with respect to bulk emission as a result of size-quantization. In addition, this blue shift indicates that the optical properties are not dominated by defect states.

Type
Research Article
Copyright
Copyright © Materials Research Society 2004

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References

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