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Molecular Adsorption and Fragmentation of Bromoform on Polyvinylidene Fluoride with Trifluoroethylene

Published online by Cambridge University Press:  01 February 2011

Carolina C. Ilie ,
Jie Xiao  and
Peter Dowben
Carolina C. Ilie
Affiliation:
[email protected]@oswego.edu, SUNY Oswego, Physics, Oswego, New York, United States
Jie Xiao
Affiliation:
[email protected], University of Nebraska - Lincoln, Physics and Astronomy, Lincoln, Nebraska, United States
Peter Dowben
Affiliation:
[email protected], University of Nebraska-Lincoln, Physics and Astronomy, Lincoln, Nebraska, United States
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Abstract

Bromoform absorption on crystalline polyvinylidene fluoride with 30% of trifluoroethylene, P(VDF-TrFE 70:30) was investigated by photoemission and inverse photoemission and found to be associative and reversible. Molecular bromoform adsorption appears to be an activated process at 120 K with enhanced adsorption following the initial adsorption of bromoform. Strong intermolecular interactions are also implicated in the presence of a weak shake off or screened photoemission final state.

Keywords

adsorptionferroelectricx-ray photoelectron spectroscopy (XPS)
Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 1134: Symposium BB – Polymer-Based Smart Materials–Processes, Properties and Application , 2008 , 1134-BB01-06
Copyright
Copyright © Materials Research Society 2009

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