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Modelling of the Near-Field Chemical Environment

Published online by Cambridge University Press:  28 February 2011

Ingmar Grenthe
Ingmar Grenthe*
Affiliation:
Grenthe Department of Inorganic Chemistry, The Royal Institute of Technology, S-100 44 Stockholm 70, Sweden
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Abstract

A review of chemical phenomena of importance for the conceptual near-field modelling of nuclear waste repositories is given. The emphasis is on thermodynamic modelling and the coupling of chemical processes mediated through ground water.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 112: Symposium P – Scientific Basis for Nuclear Waste Management XI , 1987 , 73
Copyright
Copyright © Materials Research Society 1988

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References

1. Hultqvist, G., Corr. Sci. 26(2), 173 (1986)Google Scholar
2. Marsh, G., presented at the 1987 MRS Fall Meeting, Boston, Mass. (unpublished)Google Scholar
3. Tardy, Y., Vieillard, Ph., and Fritz, B. “Geochemical modelling of the interactions between rocks, betonite, copper and the solutions around a repository for nuclear waste in granitic rock”. Report to SKB 1985 (unpublished).Google Scholar
4. Christensen, H. and Bjergbakke, E., Nucl. and Chem. Waste Manag. 6, 265 (1986).Google Scholar
5. Arnek, R., Arkiv Kemi 32, 55 (1970).Google Scholar
6. Baes, C.F. and Messmer, R.E., “The Hydrolysis of Cations” (Wilely, New York 1976).Google Scholar
7. Ciavatta, L., Juliano, M., and Porto, R., Polyhedron 6, 1283 (1987).Google Scholar
8. Johnson, L.H. and Shoesmith, D.W., “Spent Fuel” (unpublished manus)Google Scholar
9. Bruno, J., Sandino, A., Radiochim Acta 1988, in press.Google Scholar
10. Garrels, R.M. and Christ, C. L. “Solutions, Minerals and Equilibria” (Harper & Son, New York 1965).Google Scholar
11. Rai, D. and Ryan, J.L., Radiochim. Acta 30, 213 (1982).Google Scholar
12. Bruno, J., Grenthe, I., Munos, M., Mat. Res. Soc. Symp. Vol.50, 717 (1985).CrossRefGoogle Scholar
13. Bruno, J., Personal Communication.Google Scholar
14. Pingitore, N. in “Geochemical Processes at Mineral Surfaces,”, Ed. Hayes, and Davies, , ACS Symp. Ser. 323, Am. Chem. Soc. Washington, D.C. 1986.Google Scholar
15. Bancroft, M., Brown, J. and Fyfe, W., Chem. Geol. 19, 131 (1977).Google Scholar
16. Boischot, P., Durroux, M. and Sylvestre, G., Ann. Inst. Nat Recherche Argon, Ann. Argon. 1, 307 (1950).Google Scholar
17. Leeper, G.W., Ann. Rev. Plant Physiol. 3, (1952).Google Scholar
18. McBride, M., Soil Sci. Soc. Am. J. 43, 693 (1979).Google Scholar
19. Morse, J.W., Shanberg, P.M., Saito, A., and Choppin, G.R., Chem. Geol. 42, 85 (1984).Google Scholar
20. Benjamin, M. and Leckie, J., J. Coll. Interf. Sci. 79, 209 (1981).Google Scholar
21. Moge, B., Samina, J.-C. and Valence, G., Conf. report “Concentration Mechanisms of Uranium in Geological Environments” Nancy, France, 2–5 October 1987 p. 57.Google Scholar
22. Shanberg, P.M. and Morse, J.W., Unpublished data.Google Scholar
23. Keeney-Kennicutt, W.L. and Morse, J.W., Geochim. Cosmochim. Acta 49, 2577 (1985).Google Scholar
24. Davies, J., James, R. and Leckie, J., J. Coll. Interf. Sci. 63(3), 480 (1978). J. Davies and J. Leckie, Geochim. Cosmochim. Acta 7(1), 90 (1978), J. Davies and J. Leckie, Geochim. Cosmochim. Acta 74(1), 32 (1980).Google Scholar
25. Hsi, C. and Langmuir, D., Geochim. Cosmochim. Acta 49, 1931 (1985)Google Scholar
26. Balistrieri, L.S. and Murray, J., Am. J. Sci. 281, 788 (1981).Google Scholar
27. Fritz, B., Kam, M., and Tardy, Y., SKB/KBS Techn. Report 84–10. B. Fritz and M. Kam, SKB Techn. Report 85–10.Google Scholar
28. Anderson, D.M., “Smectite Alteration”, Proceedings of a Colloquium at State University of New York at Buffalo, May 26–27, 1982, KBS Technical Report 83–03.Google Scholar
29. Claesson, T., “Water-rock interaction at elevated temperatures: Chemical changes in water composition”. Diss Dept. of Geology, Chalmers Inst. of Technology, Gothenburg, Sweden, 1983.Google Scholar
30. Wikberg, P. and Axelsen, K., submitted to Appl. Geochem. 83Google Scholar
31. Jensen, B. Skytte, Riso-R-430 (Riso Nat. Lab., Denmark) 1980, (unpublished. G.R. Choppin and B. Allard in “Handbook on the Physics and Chemistry of the Actinides (A.J. Freeman, C. Keller Eds.), Amsterdam 1985 Vol.3, Chap. 11., J.l. Kim in “Handbook on the Physics and Chemistry of the Actinides (A.J. Freeman, C. Keller Eds.), Amsterdam 1985 Vol.4 Chap. 8.Google Scholar
32. Goldhaber, M.B., Mohagheghi, A., and Reynolds, R.L., Conf. report “Concentration Mechanisms of Uranium in Geological Environments” Nancy, France, 2–5 October 1985 p. 21.Google Scholar
33. Marsh, G.P., Bland, I.D., Taylor, K.J., Sharland, S.M., and, Tasker, P., An Assessment of Carbon Steel Overpacks for Radioactive Waste Disposal, Report EUR 10437 EN, published by the Commission of the European Communities (1986).Google Scholar
34. Christensen, H. and Bjergbakke, E. “Radiolysis of groundwater from spent fuel stored according to the WP-Cave concept“, SKB Report 87–21, March 1987 (unpublished).Google Scholar
35. Bruno, J., Ferri, D., Grenthe, I. and Salvatore, F., Acta Chem. Stand. A 40, 428 (1986).Google Scholar
36. Sanchez, A., Murray, J., Sibley, T., Geochim. Cosmochim. Acta 49, 2297 (1985).Google Scholar