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Modelling of The Intramolecular Structure Of Monolayer C60 Molecules Observed with Scanning Tunneling Microscopy

Published online by Cambridge University Press:  28 February 2011

T. Chen ,
S. Howells ,
M. Gallagher ,
L. Yi ,
D. Sarid ,
D. L. Lichtenberger ,
K. W. Nebesny  and
C. D. Ray
T. Chen
Affiliation:
Laboratory for Scanning Tip MicroscopyOptical Sciences CenterUniversity of Arizona, Tucson AZ 85721
S. Howells
Affiliation:
Laboratory for Scanning Tip MicroscopyOptical Sciences CenterUniversity of Arizona, Tucson AZ 85721
M. Gallagher
Affiliation:
Laboratory for Scanning Tip MicroscopyOptical Sciences CenterUniversity of Arizona, Tucson AZ 85721
L. Yi
Affiliation:
Laboratory for Scanning Tip MicroscopyOptical Sciences CenterUniversity of Arizona, Tucson AZ 85721
D. Sarid
Affiliation:
Laboratory for Scanning Tip MicroscopyOptical Sciences CenterUniversity of Arizona, Tucson AZ 85721
D. L. Lichtenberger
Affiliation:
Laboratory for Electron Spectroscopy and Surface AnalysisDepartment of ChemistryUniversity of Arizona, Tucson AZ 85721
K. W. Nebesny
Affiliation:
Laboratory for Electron Spectroscopy and Surface AnalysisDepartment of ChemistryUniversity of Arizona, Tucson AZ 85721
C. D. Ray
Affiliation:
Laboratory for Electron Spectroscopy and Surface AnalysisDepartment of ChemistryUniversity of Arizona, Tucson AZ 85721
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Abstract

Images of monolayer coverages of C60 on gold substrates, using scanning tunneling microscopy, reveal intermolecular arrangement and intramolecular features. In this paper we concentrate on the interpretation of these internal features, present a model showing that they arise from local charge density variations of high-lying π orbitals on approximately every other carbon atom, and discuss also other possible mechanisms for this effect.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 206: Symposium G – Clusters and Cluster-Assembled Materials , 1990 , 721
Copyright
Copyright © Materials Research Society 1991

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References

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