Hostname: page-component-586b7cd67f-r5fsc Total loading time: 0 Render date: 2024-11-29T07:43:00.941Z Has data issue: false hasContentIssue false

Model Compound Approach for Polymer-Metal InterFaces: ESCA Studies

Published online by Cambridge University Press:  22 February 2011

P. N. Sanda
Affiliation:
IBM Thomas J. Watson Research Center Yorktown Heights, New York 10598
J. W. Bartha
Affiliation:
IBM Thomas J. Watson Research Center Yorktown Heights, New York 10598
B. D. Silverman
Affiliation:
IBM Thomas J. Watson Research Center Yorktown Heights, New York 10598
P. S. Ho
Affiliation:
IBM Thomas J. Watson Research Center Yorktown Heights, New York 10598
A. R. Rossi
Affiliation:
Department of Chemistry University of Connecticut Storrs, Connecticut 06268
Get access

Abstract

ESCA studies of two molecules which are similar in structure to the PMDA and ODA constituents of the PMDA-ODA polyimide monomer are discussed. Their interaction with in-situ evaporated Cr and Cu films are compared. The PMDA model compound interacts with Cr through the imide group, while very little interaction is observed with Cu. The ODA model compound (oxydianiline) interacts with Cr via the ether linkage and the terminal amino groups, whereas very little interaction is observed with Cu.

Type
Research Article
Copyright
Copyright © Materials Research Society 1985

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1. Buchwalter, P.L. and Baise, A.I., in Polyimides: Synthesis, Characterization and Applications, Vol.1, Ed. Mittal, K.L., Plenum Press, New York 1984.Google Scholar
2. Silverman, B.D., Sanda, P.N., Ho, P.S. and Rossi, A.R., inpreparation.Google Scholar
3. Dupuis, M., Spangler, D. and Wendoloski, J.J., Nat. Resour. Comput. Chem. Software Catalog, Vol. 1, Prog. No. QGOl (Gamess).Google Scholar
4. Takahashi, N., Yoon, D.Y. and Parrish, W., Macromolecules, in press.Google Scholar
5. Clark, D.T., Adams, D.B., Dilks, A., Pealing, J. and Thomas, H.R., J. Electron Spectrosc. 8 51 (1976).Google Scholar
6. For comparison to previous results (see the paper by P. Hahn et. al. in this volume) the units are defined as lml = 7.84×1014atoms/cm2, corresponding to the atomic density of Si(111).Google Scholar