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Microwave Processing of Ceramics - An Overview

Published online by Cambridge University Press:  25 February 2011

Willard H. Sutton
Willard H. Sutton*
Affiliation:
United Technologies Research Center, 411 Silver Lane, MS 24, East Hartford, CT 06108
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Abstract

During the past decade, many exploratory studies and experiments have been performed on the microwave heating and processing of ceramics and composite materials. Much of this effort was stimulated by the unique and potential benefits that microwave energy can provide over conventional processing methods. While microwave processing of ceramics is still in an early developmental stage, there are many areas yet to be explored, challenges to be met, and economic and commercial payoffs to be substantiated.

Since the first MRS International Symposium on Microwave Processing in 1988, interest in this field has grown and many new developments have occurred. The purpose of this paper is to highlight some of the recent advances, to discuss the current state-of-the-art, and to suggest some future directions.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 269: Symposium L – Microwave Processing of Materials III , 1992 , 3
Copyright
Copyright © Materials Research Society 1992

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References

REFERENCES

1. Roy, R., “Dedication”, Microwave Processing of Materials, edited by Sutton, W.H., Brooks, M.H. and Chabinsky, I.J. (Matls. Res. Soc. Proc. 124, Pittsburgh, PA. 1988).Google Scholar
2. Hippel, A. von, ed., Dielectric Materials and Apnlications, Technology Press of MIT and Wiley, New York, 1954, 422 pp.Google Scholar
3. Levinson, M.L., US. Pat. No. 3, 585, 258 (15 June 1971), orig. application 19 Oct. 1965.Google Scholar
4. Osepchuk, J.M., “A History of Microwave Heating Applications,” IEEE Trans, Microwave Theory Tech., MIT–32 (9), 1200–1224 (1984).Google Scholar
5. Bennett, C.E.G., McKinnon, N.A., and Williams, L.S., “Sintering in Gas Discharges”, Nature (London), 217, 1287–1288 (1968).CrossRefGoogle Scholar
6. Schroeder, R.E. and Hackett, W.S., “Microwave Energy in the Foundry”, Br. Foundryman, 293–98 (Aug. 1971).Google Scholar
7. Metaxas, A.C. and Meredith, R.J., Industrial Microwave Heating, Peter Peregrinus Ltd., London, 1983, 357 pp.Google Scholar
8. Tinga, W.R., “Interactions of Microwave and Materials”, Int'l Microwave Power Inst., Proc. on Short Course for Users with Microwave Power, Nov. 1970.Google Scholar
9. Sutton, W.H., “Microwave Firing of High Alumina Castables”, in Ref. 1, 287–295, (1988). Work performed in 1975.Google Scholar
10. Berteaud, A.J. and Badot, J.C., “High Temperature Microwave Heating in Refractory Materials”, J. Microwave Power, 11 (4), 315–20 (1976).Google Scholar
11. Nishitani, T., US. Pat. No. 4,147,911 (3 April 1979)Google Scholar
12. Haas, P.A., “Heating of Uranium Oxides in a Microwave Oven”, Am. Ceram. Soc. Bull., D8 (9), 873 (1979).Google Scholar
13. Chabinsky, I.J. and Eves, E.E. III, “The Application of Microwave Energy in Drying, Calcining, and Firing of Ceramics”, InterCeram, 6 (Dec. 1986), 30–35.Google Scholar
14. Oda, S.J. and Balbaa, I.S., “Microwave Processing at Ontario Hydro Research Division”, in Ref. 1, 303–309, (1988).Google Scholar
15. Schubring, N.W., “Microwave Sintering of Alumina Spark Plug Insulators”, Tech. Rept., GMR–4471, General Motors Research Laboratory, 1983, pp. 1–27.Google Scholar
16. Qudmendur, L., Choisnet, J., Raveau, B., Thiebaut, J.M., and Roussy, G., “Microwave Clinkering with a Grooved Resonant Applicator”, J. Am. Cer. Soc., 66 (12), 855–59 (1983).Google Scholar
17. MacDowell, J.F., “Microwave Heating of Nepheline Glass-Ceramics”, Am. Cer. Soc. Bull., 63 (2), 282–286, (1984).Google Scholar
18. Hiissler, Y. and Johansen, L., “Microwave Heating of Fused Quartz to High Temperatures in the Fabrication Process of Optical Fibers”, in Ref. 1, 273–278 (1988).Google Scholar
19. Sutton, W.H., “Microwave Processing of Ceramics”, Am. Cer. Soc. Bull., 68 (2), 376–386 (1989).Google Scholar
20.Masao, Japanese Patent 153793/86 (30 Jun 86).Google Scholar
21. Meek, T.T. and Blake, R.D., US. Patent 4,529,857 (16 July 1985).Google Scholar
22. Meek, T.T. and Blake, R.D., “Ceramic-Ceramic Seals by Microwave Heating”, J. Matls. Sci. Lett., 5 270–74 (1986).Google Scholar
23. Palaith, D., Silberglitt, R., Wu, C.C. M., Kleiner, R., and Libelo, E., “Microwave Joining of Ceramics”, in Ref. 1, 255–266, (1988), Bull. Am. Cer. Soc. 68 (9), 1601 (1989).Google Scholar
24. Fukushima, H., Yamaka, T., and Matsui, M., “Microwave Heating of Ceramics and Its Application to Joiningr”, in Ref. 1, 267–282, (1988), J. Matls. Res. 5 (2), 397-405 (1990).Google Scholar
25. Sheppard, L., “Manufacturing Ceramics with Microwaves: The Potential for Economic Production”, Am. Cer. Soc. Bull., 67 (10), 1556–61 (1988).Google Scholar
26. Sutton, W.H., Brooks, M.H., and Chabinsky, I.J., editors, Microwave Processing of Materials, (Matls. Res. Soc. Proc. 12, Pittsburgh, PA, 1988).Google Scholar
27. Snyder, W.B. Jr, Sutton, W.H., Iskander, M.F., and Johnson, D. Lynn, editors, Microwave Processing of Materials II (Matls. Res. Soc. Proc. 169 Pittsburgh, PA 1990).Google Scholar
28. Clark, D.E., Gac, F.D., and Sutton, W.H., editors, Microwave Theory and Annlication in Materials Processing, Cer. Trans. 21, Amer. Cer. Soc. (1991).Google Scholar
29. Beatty, R.L., Sutton, W.H., and Iskander, M.F., editors, Microwave Processing of Materials III, (Matls. Res. Soc. Proc. 269, 1992, this Volume).Google Scholar
30. Asmussen, J. and Garard, R., “Precision Microwave Applicators and Systems for Plasma said Materials Processing”, in Ref. 26, 347–352 (1988).Google Scholar
31. Tian, Y-L., “Practices of Ultra-Rapid Sintering of Ceramics Using Single Mode Applicators”, in Ref. 28, 283–300 (1991).Google Scholar
32. Tian, B.Q. and Tinga, W.R., “A Wide Range Tunable and Matchable High Temperature Applicator”, in Ref. 28, 647–654 (1991).Google Scholar
33. Gerling, J.F., “Techniques to Improve the Performance of Microwave Process Systems Which Will Utilize High Q Cavities”, in Ref. 28, 667–674 (1991).Google Scholar
34. Sa'adaldin, H.S., Black, N.M., Ahmad, I. and Silberglitt, R., “Efficient Coupling with an Adjustable Compound Iris for Joining of SiC in a Single Mode Applicator”, this Volume.Google Scholar
35. Kimrey, H.D., Kiggans, J.O., Janney, M.A., and Beatty, R.L., “Microwave Sintering of Zirconia-Toughened Alumina Composite”, in Ref. 27,243–255 (1991).Google Scholar
36. Janney, M.A., Calhoun, C.L., and Kimrey, H.D., “Microwave Sintering of Zirconia-8 mol % Yttria”, in Ref. 28,311–318 (1991).Google Scholar
37. Janney, M.A., Calhoun, C.L. and Kimrey, H.D., “Microwave Sintering of Solid Oxide Fuel Cell Materials, I: Zirconia-8 mol % Yttria”, J. Am. Cer. Soc., 75 (2), 341–346 (1992).Google Scholar
38. Dd, A., Ahmad, I., Whitney, E.D., and Clark, D.E., “Microwave (Hybrid) Heating of Alumina at 2.45 GHz: I. Microstructural Uniformity and Homogeneity”, in Ref. 28, 319–328, (1991); II. Effect of Processing Variables, Heating Rates and Particle Size”, ibid, 329-339.Google Scholar
39. Cozzi, A.D., Jones, D.K., Fathi, Z., and Clark, D.C., “Microstructural Evaluation of YBa2Cu3O7-x Using Microwave Energy” Ref. 28, 357–364 (1991).Google Scholar
40. Fang, Y., Agrawal, D.K., Roy, D. M., and Roy, R., “Rapid Sintering of Hydoxyapatite Ceramics by Microwave Processing”, in Ref. 28, 349–356 (1991).Google Scholar
41. Harrison, W.B., Hanson, M.R.B., and Koepke, B.G., “Microwave Processing and Sintering of PZT and PLZT Ceramics”, in Ref. 26, 279–295 (1988).Google Scholar
42. Patterson, M.C.L., Aptd, P.S., Kimber, R.M., and Roy, R., “A High Performance Tool Bit Produced by Microwave Heating”, presented at UIE Microwaves and Radio Frequency Conference, pp. 33–36; Nice, France, Oct. 8-10, 1991.Google Scholar
43. Patterson, M.C.L., Apté, P.S., Kimber, R.M., and Roy, R., “Batch Process for Microwave Sintering of Si3N4”, this Volume; and “Mechanical and Physical Properties of Microwave Sintered Si3N4”, this Volume.Google Scholar
44. Smith, R., Iskander, M.F., Andrade, O.M., and Kimrey, H., “Finite Difference Time-Domain (FDTD) Simulation of Microwave Sintering in Multimode Cavities”, this Volume.Google Scholar
45. Janney, M.A. and Kimrey, H.D., “Microwave Sintering of Alumina at 28 GHz”, Cer. Trans. Vol, I. Ceramic Powder Science II-B. Am. Cer. Soc., 919–924 (1988).Google Scholar
46. Swain, B., “Microwave Sintering of Ceramics”, Adv. Matls. and Processes, 134(30) 76–81 (1988)Google Scholar
47. Meek, T.T., Blake, R.D., and Petrovic, J.J., “Microwave Sintering of Al2O3 and Al2O3-SiC-Whisker Composites”, Cer. Eng. Sci. Proc., 8 (7-8), 861–71 (1987).Google Scholar
48. Bykov, Y., Goldenberg, A.F.L., and Flyagin, V.A., “The Possibilities of Material Processing by Intense Millimeter-Wave Radiation”, in Ref. 27, 41–42 (1991).Google Scholar
49. Paton, B.E. and Sklyarevich, V.E., “Application of Gyrotron Radiation for Coating and Welding”, in Ref. 27, 99–100 (1991).Google Scholar
50. Sklyarevich, V., Detkov, A., Shevelev, M., and Decker, R., “Interaction of Gyrotron Radiation with Powder Materials”, this Volume.Google Scholar
51. Tian, Y-L. and Johnson, D. Lynn, “Microwave Sintering of Al2O3-TiC Composites”, Cr. Trans. Vol. I. Ceramic Powder Science II-B, Am. Cer. Society, 933–938 (1988).Google Scholar
52. Kao, Y.H. and MacKenzie, J.D., “Magnetite as a Sintering Aid for Microwave Consolidation of Soda-Lime Glass”, in Ref. 28, 341–348 (1991).Google Scholar
53. Tian, Y-L, Li, B-S., Guo, J-K., and Yan, D-S., “A Microwave Processing System for Ceramics with Improved Energy Efficiency and Processing Control”, 25th Microwave Power Symposium, Int'l Microwave Power Inst., 13-14, Denver (Aug 1990).Google Scholar
54. Tian, Y-L., and Johnson, D.L., “Ultrafine Microstructure of Al2O3 Produced by Microwave Sintering”, Cer. Trans. Vol. I. Ceramic Powder Science II-B, American Ceramic Soc., 925–931 (1991).Google Scholar
55. Patil, D.S., Mutsuddy, B.C., Gavulic, J., and Dahimene, M., “Microwave Sintering of Alumina Ceramics in a Single Mode Applicator”, in Ref. 28, 301–309 (1991).Google Scholar
56. Tian, Y-L., Li, B-S., Shi, J-L., Xu, Y-P., Guo, J-K, and Yen, D-S, “Microwave Sintering of Y2O3 (3%)-ZrO2 (TZP)”, in Ref. 28, 577–584 (1991).Google Scholar
57. Janney, M.A., Kimrey, H.D., and Kiggans, J.O., “Microwave Processing of Ceramics: Guidelines Used at the Oak Ridge National Laboratory”, this Volume.Google Scholar
58. Katz, J.D., and Blake, R.D., “Microwave Sintering of Multiple and Composite Components”, Bull. Am. Cer. Soc. 70 (8), 1304–1308 (1991).Google Scholar
59. Patterson, M.C.L., Kimber, R.M., and Aptd, P.S., “The Properties of Alumina Sintered in a 2.45 GHz Microwave Field”, in Ref. 27, 257–266 (1991).Google Scholar
60. Hamlyn, M.G., and Bowden, A.L., “Microwave Processing of Earthenware Ceramics”, Bull. Am. Cer. Soc., 69 (3), 368, 370, 372 (1990).Google Scholar
61. Krage, M.K., “Microwave Sintering of Ferrites”, Am. Cer. Soc. Bull., 60 (11), 1232–34 (1981).Google Scholar
62. Hendrix, W.A., and Martin, T., “An Experimental Investigation of Hybrid Convective/Microwave Drying of Electrical Porcelain”, this Volume.Google Scholar
63. Smith, F., “Choosing the Right Electromagnetic Heat Process”, Automation, 38 (12), 42–44 (1991).Google Scholar
64. Balomey, J-C., and Metail, J-P., “Review of the French Activity in Microwave Control and Processing of Materials”, in Ref. 27, 15–26 (1991).Google Scholar
65. Ochiai, T., Ikdea, M., and Nishitani, T., “Application of Microwave Drying to Monolithic Ladle Linings”, Taikabutsu Overseas, 1 (2), 92–96 (1981).Google Scholar
66. Holcombe, C.E., and Dykes, N.L., “Importance of ‘Casketing’ for Microwave Sintering of Materials”, J. Matls. Sci. Letters, 9, 425–428 (1990).Google Scholar
67. Holcombe, C.E., and Dykes, N.L., “Microwave Sintering of Titanium Diboride”, J. Matls. Sci., 26, 3730–3738 (1991).Google Scholar
68. Holcombe, C.E. and Dykes, N.L., “Ultra High Temperature Microwave Sintering”, in Ref. 28, 375–386 (1991).Google Scholar
69. Katz, J.D., Blake, R.D., Petrovic, J.J., and Scheinberg, H., “Microwave Sintering of Boron Carbide”, in Ref. 26, 219–226 (1988).Google Scholar
70. Tiegs, T.N., Kiggans, J.O. Jr, and Kimrey, H.D., “Microwave Processing of Silicon Nitride”, in Ref. 28, 267–272 (1991).Google Scholar
71. Tiegs, T.N., Ferber, M.K., Kiggans, J.O., More, K.L., Hubbard, C.M., and Coffey, D.W., “Microstructure Development During Microwave Annealing of Dense Silicon Nitride”, in Ref. 28, 411–417 (1991).Google Scholar
72. Ahmad, I., Chandler, G.T., and Clark, D.E., “Processing of Superconducting Ceramics Using Microwave Energy”, in Ref. 26, 239–246 (1988).Google Scholar
73. Moore, E.H., Ahmad, I., and Clark, D.E., “Microwave Thermogravimetric Thermal Analyzer (MTGA)”, in Ref. 28, 675–681 (1991).Google Scholar
74. Moore, E.H., Clark, D.E., and Hutchen, R., “Polymethyl Methracrylate Binder Removal from an Alumina Compact: Microwave vs. Conventional Heating”, this Volume.Google Scholar
75. Dalton, R.C., Ahmad, I., and Clark, D.E., “Combustion Synthesis Using Microwave Energy”, Cer. Eng. Sci. Proc. 11(10), 1729–1742 (1990).Google Scholar
76. Evans, J.W., and Gupta, D., “A Mathematical Model for Microwave-Assisted Chemical Vapor Infiltration”, in Ref. 27, 101–107 (1991).Google Scholar
77. Devlin, D.J., Currier, R.P., and Barbero, R.S., “Microwave Assisted Chemical Vapor Infiltration”, presented at the 1991 MRS Fall Meeting, Boston, MA (1991) (unpublished).Google Scholar
78. Willert-Porada, M.A. and Vodegel, S., “Metallorganic and Microwave-Processing of Ceramic Powders and Compacts”, in Ref. 28, 631–638 (1991).Google Scholar
79. Willert-Porada, M.A., “Metallorganic and Microwave-Processing of Monolithic and Polyphasic Ceramics”, this Volume.Google Scholar
80. Kiggians, J.O., Hubbard, C.R., Steele, R.R., Kimrey, H.D., Holcombe, C.E., and Tiegs, T.N., “Characterization of Silicon Synthesized by Microwave Sintering”, in Ref. 28, 403–410 (1991).Google Scholar
81. Kiggians, J.O. and Tiegs, T.N., “Characterization of Sintered Reaction-Bonded Silicon Nitride Processed by Microwave Heating”, this Volume.Google Scholar
82. Thomas, J.J., Johnson, D.L., Jennings, H.M., Jesse, R.R., and Faber, K.T., “Nitriding of Nonisothermal Si Compacts Using Microwave Heating”, this Volume.Google Scholar
83. Binner, J.G.P., Al-Dawery, I.A., Aneziris, C., and Cross, T.E., “Use of the Inverse Temperature Profile in Microwave Processing of Advanced Ceramics”, this Volume.Google Scholar
84. Adrian, D.J., US Patent No. 4,930,673 (3 July 1990).Google Scholar
85. Apté, P.S. and Pant, A., US Patent No. 5,010,220 (23 April 1991).Google Scholar
86. Kingston, H.M. and Jassie, L.B., “Introduction to Microwave Sample Prenariation. Themy, and Practice”, Amer. Chem. Soc. Ref. Book, Washington, DC (1988).Google Scholar
87. Pougnet, M., Michelson, S., and Downing, B., “Computer Controlled Microwave Waveguide for Sample Heating and Dissolution”, J. Intl Microwave Power Inst., 26 (3), 139–144 (1991).Google Scholar
88. Lydtin, H. and Ritz, A., “Uniform Low-Temperature Deposition of Optical Layers by Plasma-Activated CVD”, this Volume.Google Scholar
89. Lauf, R.J., Hanby, C., Holcombe, C.E., and Vierow, W.F., “Microwave Processing of Tantalum Capacitor Anodes”, this Volume.Google Scholar
90. Lauf, R.J., Holcombe, C.E., and Hanby, C., “Microwave Sintering of Multilayer Ceramic Capacitors”, this Volume.Google Scholar
91. Gielisse, P.J., Niculescu, H., and Roy, B., “Applications of Microwaves in High Temperature Superconductor Materials and Devices”, in Ref. 28, 613–621 (1991).Google Scholar
92. Fathi, Z., Ahmad, I., Simmons, J.H., and Clark, D.E., “Surface Modification of Sodium Aluminosilicate Glasses Using Microwave Energy”, in Ref. 28, 623–629 (1991).Google Scholar
93. Fathi, Z. and Clark, D.E., “Surface Modification of Ceramics Using Microwave Energy”, this Volume.Google Scholar
94. Jin, M. and Kao, K.C., “Characterization of the ECR Microwave Plasma Etching System”, this Volume.Google Scholar
95. Sturken, E.F., “The Use of ‘Self-Heating’ Ceramics as Crucibles for Microwave Melting of Metals and Nuclear Waste Glass”, in Ref. 28, 433–440 (1991).Google Scholar
96. Jantzen, C.M. and Cadieux, J.R., “Characterization of Radioactive Waste Melter Feed Vitrified by Microwave Energy”, in Ref. 28,441–449 (1991).Google Scholar
97. Schulz, R.L., Fathi, Z., and Clark, D.E., “Microwave Processing of Simulated Nuclear Waste Glass”, in Ref. 28, 451–458 (1991).Google Scholar
98. Oda, S.J., “Microwave Processing of Hazardous Materials-Present and Future Opportunities”, this Volume.Google Scholar
99. Kumar, S.N., Pant, A., Sood, R.R., Ng-Yelim, J., and Holt, R.T., “Production of Ultrafine Silicon Carbide by Fast Firing in Microwave and Resistance Furnaces”, in Ref. 28, 395–402 (1991).Google Scholar
100. Singh, A.K., Mehta, P., and Kingon, A.I., “Synthesis of Nonoxide Ceramic Powders by Nonthermal Microwave Plasma”, in Ref. 28, 421–429 (1991).Google Scholar
101. Kladding, W.F. and Horn, J.E., “Submicron Oxide Powder Preparation by Microwave Processing”, Ceramics International, 16 (1), 99–106 (1990).Google Scholar
102. Vollath, D., Sickafus, K.E., and Varma, R., “Electron Microscopy Study on Zirconia and Alumina Ceramic Powders Synthesized by Microwave Plasma Pyrolysis”, this Volume.Google Scholar
103. Eastman, J.A., Sickafus, K.E., Katz, J.D., Boeke, S.G., Blake, R.D., Evans, C.R., Schwartz, R.B., and Liao, Y.X., “Microwave Sintering of Nanocrystalline TiO2 ”, in Ref. 27, 273–278 (1991).Google Scholar
104. Yiin, T.Y., Varadan, V.V., and Varadan, V.K., “Microwave Joining of Si-SiC/Al/Si-SiC”, in Ref. 28, 507–514 (1991).Google Scholar
105. Silberglitt, R., Palaith, D., Black, W.M., Sa'adaldin, H.S., Katz, J.K., and Blake, R.D., “Investigation of Interlayer Materials for the Microwave Joining of SiC”, in Ref. 28, 487–495 (1991).Google Scholar
106. Abmad, I., Silberglitt, R., Black, W.M., Sa'adaldin, H.S., and Katz, J., “Microwave Joining of Silicon Carbide Using Several Different Approaches”, this Volume.Google Scholar
107. Yu, X.D., Varadan, V.V., and Varadan, V.I., “Application of Microwave Processing to Simultaneous Sintering and Joining of Ceramics”, in Ref. 28,497–503 (1991).Google Scholar
108. Al-Assafi, S., Ahmad, I., Fathi, Z., and Clark, D.E., “Microwave Joining of Ceramics”, in Ref. 28, 515–521 (1991).Google Scholar
109. Al-Assafi, S. and Clark, D.E., “Microwave Joining of Ceramics: A Study on Joining Alumina Both Directly and With Alumina Gel”, this Volume.Google Scholar
110. Ahmad, I., Dalton, R., and Clark, D., “Unique Application of Microwave Energy to the Processing of Ceramic Materials”, J. Microwave Power and Electromagnetic Energy, 26 (3) 128–138 (1991).Google Scholar