Hostname: page-component-cd9895bd7-gvvz8 Total loading time: 0 Render date: 2024-12-27T01:50:02.215Z Has data issue: false hasContentIssue false

Microstructural Developments During Implantation of Metals

Published online by Cambridge University Press:  25 February 2011

D. I. Potter
Affiliation:
Metallurgy Department and Institute of Materials Science, University of Connecticut, Storrs, CT 06268
M. Ahmed
Affiliation:
Metallurgy Department and Institute of Materials Science, University of Connecticut, Storrs, CT 06268
S. Lamond
Affiliation:
Metallurgy Department and Institute of Materials Science, University of Connecticut, Storrs, CT 06268
Get access

Abstract

The chemical and microstructural changes caused by the direct implantation of solutes into metals are examined. The particular case involving Al+-ion implantation into nickel is treated in detail. Chemical composition profiles measured using Auger spectroscopy and Rutherford backscattering, and average near-surface chemical composition measured using an analytical electron microscope, are compared with model calculations. The microstructures that develop during implantation are investigated using transmission electron microscopy. For low fluences implanted near room temperature, these microstructures contain dislocations and dislocation loops. Dislocation loops, dislocations, and voids result from implantations at temperatures near 500°C. Higher fluences at these elevated temperatures produce precipitates when the composition of implanted solute lies in a two-phase region of the phase diagram. Implanted concentrations corresponding to intermetallic compounds produce continuous layers of these compounds. Room temperature, as compared to elevated temperature, implantation may produce the same phases at the appropriate concentrations, e.g. β'-NiAl, or different phases, depending on the relative stability of the phases involved.

Type
Research Article
Copyright
Copyright © Materials Research Society 1984

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Dearnaley, G., J. Metals 35, 1828 (1982).Google Scholar
2. Potter, D. I., Ahmed, M., and Lamond, S., J. Metals 35, 1722 (1983).Google Scholar
3. Hansen, M., Constitution of Binary Alloys (McGraw-Hill, New York 1958) 118.Google Scholar
4. Goldstein, J. I. in: Intro. to Analytical Electron Microscopy, Hren, J., Goldstein, J. and Joy, D., eds. (Plenum Press, New York 1979) pp. 83120.Google Scholar
5. Biersack, J. P. and Haggmark, L. G., Nucl. Inst. and Methods 174, 257269 (1980)Google Scholar
6. Anttila, A., Bister, M. and Forrtell, A., Rad. Effects 33, 1319 (1977).Google Scholar
7. Liau, Z. L. and Mayer, J. W. in: Treatise on Materials and Technology, Vol. 18, Hirvonen, J. K., ed. (Academic Press, New York 1980) pp. 1750.Google Scholar
8. Namavar, F., Budnick, J. I., Hayden, H. C., Otter, F. A. and Patarini, V., these proceedings.Google Scholar
9. Kräutle, H., Nucl. Inst. and Methods 134, 167172 (1976).Google Scholar
10. Farkas, D., Singer, I. L., and Rangaswamy, M., Abstracts Fall Meeting Metallurgical Soc. AIME, Philadelphia, PA (1983), p. 54.Google Scholar
11. Robinson, T. M. and Jenkins, M. L., Phil. Mag. A 43, 9991015 (1981).Google Scholar
12. Hall, B. O. and Potter, D. I., in Effects of Irradiation on Structural Materials, Sprague, J. A. and Kramer, D., eds. (American Society of Testing and Materials, Philadelphia, PA 1979) pp. 3245.Google Scholar
13. Radiation Effects in Breeder Reactor Structural Materials, Bleiberg, M. L. and Bennett, J. W., eds. (Metallurgical Society of AIME, New York 1977).Google Scholar
14. Wiedersich, H., Rad. Effects 12, 111125 (1972).Google Scholar
15. Lamond, S. and Potter, D. I., J. Nuclear Materials 117, 6469 (1983).Google Scholar
16. Johnson, E., Wohlenberg, T., and Grant, W. A., Phase Trans. 1, 2334 (1979).Google Scholar
17. Enami, E., Nenno, S. and Shimizu, K., Trans. Japan Inst. of Metals 14, 161165 (1973).Google Scholar
18. Reynaud, P. F., J. Appl. Cryst. 9, 263268 (1976).Google Scholar
19. Grunes, L. A., Barbour, J. C., Hung, L. S., Mayer, J. W. and Ritsko, J. J., these proceedings.Google Scholar
20. Phase Transformations During Irradiation, Nolfi, F. Jr. ed. (Applied Science Pub., Essex, England 1983),Google Scholar
also Phase Stability During Irradiation, Holland, J. R., Mansur, L. K. and Potter, D. I., eds. (Metallurgical Society of AIME, Warrendale, PA 1981).Google Scholar