Hostname: page-component-586b7cd67f-tf8b9 Total loading time: 0 Render date: 2024-11-25T15:40:50.488Z Has data issue: false hasContentIssue false

Micropatterned Polythiophene Nanofibers via Electrostatic Spinning and Photolithography

Published online by Cambridge University Press:  01 February 2011

Chris Ik Asemota
Affiliation:
[email protected], University Of Connecticut, Polymer Science, N.Eagleville Rd, Storrs, CT, 06269, United States
Arvind Kumar
Affiliation:
[email protected], University of Connecticut, Polymer Program, Institute of Materials Science, University of Connecticut, 97 North Eagleville Road, Storrs, CT, 06269, United States
Gregory A Sotzing
Affiliation:
[email protected], University of Connecticut, Polymer Program, Institute of Materials Science, University of Connecticut, 97 North Eagleville Road, Storrs, CT, 06269, United States
Get access

Abstract

Herein we report the patterning of large conducting polymer nanofiber mats of the polyterthiophene precursor, into regular micron scale arrays of smaller mats each of which has the potential of being independently addressed. These fiber grids, micro mats of conducting polymer fibers, were prepared by the combined techniques of electrospinning, soft photolithography, and solid state electrochemical crosslinking. The micro size mats are shown to retain their electrochromic behavior, subject to expected degradation in air as reported in the literature. Our contribution to the investigation of conducting polymers in display technology is oriented towards processibility and preparation of regular conducting polymer structures.

Type
Research Article
Copyright
Copyright © Materials Research Society 2007

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Sotzing, , et al. Adv. Mater., 2005, 17, 21772180.Google Scholar
2. Otero, T.F., M.T. Cortes. Adv. Mater., 15 (2003) 279–282 Google Scholar
3. Sapp, S. A., Sotzing, G. A., J. R. Reynolds. Chem. Mater., 1998. 10. 2101 Google Scholar
4. Carpi, F., Rossi, D. De, J. Optics and Laser Technology., 38. 2006. 292–305 Google Scholar
5. Friend, R. H, et al, Nature., 397 (1999) 121 Google Scholar
6. Jang, S; Sotzing, G. A.; Marquez, M Poly(thiophene)s Prepared via Electrochemical Solid-State Oxidative Cross-Linking. A Comparative Study Macromolecules 2004, 37(12), 43514359.Google Scholar