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Metal Cyanide Networks Formed at an Air-Water Interface: Structure and Magnetic Properties

Published online by Cambridge University Press:  18 March 2011

Jeffrey T. Culp ,
A. Nicole Morgan ,
Mark W. Meisel  and
Daniel R. Talham
Jeffrey T. Culp
Affiliation:
Department of Chemistry, University of Florida, Gainesville, FL
A. Nicole Morgan
Affiliation:
Department of Physics, University of Florida, Gainesville, FL
Mark W. Meisel
Affiliation:
Department of Physics, University of Florida, Gainesville, FL
Daniel R. Talham
Affiliation:
Department of Chemistry, University of Florida, Gainesville, FL
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Abstract

Extended two-dimensional coordinate covalent networks have been formed at an air-water interface by condensing a Langmuir monolayer of an amphiphillic pentacyanoferrate(III) complex and aqueous nickel(II) ions. The cyanide-bridged arrays were transferred to solid supports by the Langmuir-Blodgett (LB) technique. The resulting thin films were structurally characterized by UV-Vis and FT-IR spectroscopies, X-ray diffraction, X-ray photoelectron spectroscopy (XPS), and SQUID magnetometry. Magnetic measurements on the thin films transferred to Mylar show evidence for ferromagnetic exchange interactions between the S = 1/2 Fe(III) and S = 1 Ni(II) centers.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 658: Symposium GG – Solid-State Chemistry of Inorganic Materials III , 2000 , GG5.2
Copyright
Copyright © Materials Research Society 2001

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References

REFERENCES

1. Comprehensive Supramolecular Chemistry, edited by Atwood, J. L. et al. (Pergamon, New York, 1996) vol. 1–11.Google Scholar
2. Berseth, P. A., Sokol, J. J., Shores, M. P., Heinrich, J. L., Long, J. R., J. Am. Chem. Soc. 122, 9655 (2000).Google Scholar
3. Fujita, M., Yazaki, J., Ogura, K., J. Am. Chem. Soc. 112, 5645 (1990).Google Scholar
4. Hoskins, B. F., Robson, R., Slizys, D. A., J. Am. Chem. Soc. 119, 2952 (1997).Google Scholar
5. Armand, F., Sakuragi, H., Tokumaru, K., New. J. Chem. 17, 351 (1993).Google Scholar
6. Buser, H. J.; Schwarzenbach, D., Petter, W.; Ludi, A., Inorg.Chem. 16, 2704 (1977).Google Scholar
7. Nakamoto, K., Infrared and Raman Spectra of Inorganic and Coordination Compounds, 3rd ed. (Wiley, New York, 1978) p. 259.Google Scholar
8. Hrepic, N. V., Malin, J. M., Inorg. Chem. 18, 409 (1979).Google Scholar
9. Ferlay, S., Mallah, T., Ouahes, R., Veillet, P., Verdaguer, M., Nature 378, 701 (1995).Google Scholar
10. Gadet, V., Bujoli-Doeuff, M., Force, L., Verdaguer, M. et al, in Magnetic Molecular Materials, edited by Gatteschi, D. et al (NATO ASI Series E, 1991) vol. 198, pp. 281–295.Google Scholar