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Mechanisms of Mound Coarsening in Unstable Epitaxial Growth
Published online by Cambridge University Press: 10 February 2011
Abstract
The effects of various island and mound relaxation mechanisms on the mound morphology and asymptotic mound coarsening exponent n are investigated for growth on fcc/bcc(001) and fcc (111) metal surfaces. While the strength of the diffusion bias (due for example to an Ehrlich-Schwoebel step barrier) affects the crossover time, the presence or absence of corner diffusion is found to play a crucial role in determining the asymptotic value of the coarsening exponent. In the absence of island-relaxation or in the case of island-relaxation without rapid corner diffusion the asymptotic exponent is found to satisfy n ≃ 1/4. However, when rapid corner-diffusion is allowed, the coarsening exponent is found to approach 1/3. For the case of reversible island growth a strong step-barrier leads to an effective corner diffusion so that a growth exponent of either 1/4 or 1/3 may be observed depending on the strength of the step-barrier. These results appear to account for recent experimental observations of a large coarsening exponent (n ≃ 0.33) in epitaxial growth of Rh/Rh(111) at high temperature as well as of a smaller coarsening exponent (n ≃ 1/4) observed in epitaxial growth of Fe/Fe(001) and Cu/Cu(001). An explanation for these results is also presented in terms of the effects of corner diffusion on the surface current and mound morphology.
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- Copyright © Materials Research Society 1999
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