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Luminescent Oxide Gels

Published online by Cambridge University Press:  25 February 2011

Mark D. Newsham ,
Michael K. Cerreta ,
Kris A. Berglund  and
Daniel G. Nocera
Mark D. Newsham
Affiliation:
Department of Chemistry, Michigan State University, East Lansing, MI 48824
Michael K. Cerreta
Affiliation:
Departments of Agricultural and Chemical Engineering, Michigan State University, East Lansing, MI 48824
Kris A. Berglund
Affiliation:
Departments of Agricultural and Chemical Engineering, Michigan State University, East Lansing, MI 48824
Daniel G. Nocera
Affiliation:
Department of Chemistry, Michigan State University, East Lansing, MI 48824
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Abstract

Luminescent oxide gels were prepared by hydrolysis of silicon alkoxides in solutions containing the luminescent hexanuclear molybdenum cluster Mo6Cl12. The resulting gel exhibited emission and lifetime behavior characteristic of Mo6Cl12 thereby indicating that the excited-state properties of the metal cluster species are not significantly perturbed by the gel environment.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 121: Symposium H – Better Ceramics Through Chemistry III , 1988 , 627
Copyright
Copyright © Materials Research Society 1988

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References

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