Hostname: page-component-586b7cd67f-dsjbd Total loading time: 0 Render date: 2024-11-23T16:33:28.900Z Has data issue: false hasContentIssue false

LixCn as Anode Material for Lithium Ion Batteries

Published online by Cambridge University Press:  26 February 2011

Haiming Xie
Affiliation:
[email protected], Northeast Normal University, Department of Chemistry, 5268,Renmin street, Changchun,Jilin, 130024, China, People's Republic of, +86-431-5099511, +86-431-5099511
Haiying Yu
Affiliation:
[email protected], Northeast Normal University, Institute of Functional Materials, Department of Chemistry, 5268, renmin street, Changchun, Jilin, 130024, China, People's Republic of
Abraham F. Jalbout
Affiliation:
[email protected], The University of Arizona, NASA Astrobiology Institute and The Department of Chemistry, Tucson, AZ, 85721, United States
Guiling Yang
Affiliation:
[email protected], Northeast Normal University, Institute of Functional Materials, Department of Chemistry, 5268, renmin street, Changchun, Jilin, 130024, China, People's Republic of
Xiumei Pan
Affiliation:
[email protected], Northeast Normal University, Institute of Functional Materials, Department of Chemistry, 5268, renmin street, Changchun, Jilin, 130024, China, People's Republic of
Rong-Shun Wang*
Affiliation:
[email protected], Northeast Normal University, Institute of Functional Materials, Department of Chemistry, 5268, renmin street, Changchun, Jilin, 130024, China, People's Republic of
*
Corresponding author: Tel: +86-431-5099511; Fax: +86-431-5099511. E-mail address: [email protected] (Rong.Shun.Wang)
Get access

Abstract

We design a way that the anode hosts provide lithium ion in lithium ion battery operation. If the limiting factors of the cathode materials are less, there will be more alternatives for it. It was proven to be successful by two kinds of test cells based on LixCn as anode material, and β-FeOOH or Cr8O21 as cathode materials. Their theoretical capacities are much higher than those present electrode materials. Unlike the lithium secondary batteries with lithium metal foil or lithium alloy as anode, this type of lithium ion batteries with LixCn as anode prohibit dendrite formation during charging-discharge process. The idea of lithium ion sources coming from the anode can come true successfully as a result that steady protecting solution be sought for LixCn.

Keywords

Type
Research Article
Copyright
Copyright © Materials Research Society 2007

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1. Tarascon, J. M., Armand, M., Nature, 414, 359 (2001).Google Scholar
2. Mizushima, K., Jones, P. C., Wiseman, P. C., and Goodenough, J. B., Mater. Res.Bull., 15, 783 (1980).Google Scholar
3. Thomas, M. G. S. R., David, W. I. F., Goodenough, J. B., and Groves, P., Mater. Res.Bull., 20,1137 (1985).Google Scholar
4. Thackeray, M. M., David, W. I. F., Bruce, P. G., and Goodenough, J. B., Mater. Res.Bull., 18, 461 (1983).Google Scholar
5. Hatanaka, H., Okami, K., Yamaura, J., Kogetsu, Y., Tanaka, N., and Saito, T., The 41st Battery Symposium of Japan, Extended Abstracts, 438, Nagoya, Japan (Oct 2000)Google Scholar
6. Saito, T., Machida, M., Yamamoto, Y., and Nagamine, M., Abstracts of the 68th Meeting of The Electrochemical Society of Japan, 236 (2001).Google Scholar
7. Saito, T., Machida, M., Yamamoto, Y., and Nagamine, M., Abstract 180, The Electrochemical Society and the International Society of Electrochemistry Meeting Abstracts, Sept 2–7, 2 (2001).Google Scholar
8. Padhi, A. K., Nanjundaswamy, K. S., and Goodenough, J. B., J. Electrochem. Soc., 144, 1188 (1997).Google Scholar
9. Chena, Z. H., and Dahn, J. R., J. Electrochem. Soc., 149 (9), A1184–A1189 (2002).Google Scholar
10. Amine, K., Yasuda, H., and Yamachi, M., J. power Source, 8182 221 (1999).Google Scholar
11. Funabiki, A., Yasuda, H., and Yamachi, M., J. power Source, 119121, 290 ( 2003).Google Scholar
12. Wang, X., Chen, X. and Zhang, Z., J. Materials Chemistry, 14, 905 (2004).Google Scholar
13. Norby, P., Christensen, A. N., Fjellvag, H. and Nielsen, M., J. Solid State Chemistry, 94, 281 (1991).Google Scholar
14. Takeda, Y., Kanno, R., Tsuji, Y. and Yamamoto, O., J. Electrochem. Soc., 131, 2006 (1984).Google Scholar
15. Yamamoto, O., Takeda, Y., Kanno, R., Oyabe, Y. and Shinya, Y., J. power Source, 20, 151 (1987).Google Scholar
16. Flynn, C. M. Jr., Chem. Rev., 84, 31 (1984).Google Scholar
17. besenhard, J. O. and Schwake, M., J. power Source, 26, 409 (1989).Google Scholar