Hostname: page-component-cd9895bd7-gbm5v Total loading time: 0 Render date: 2024-12-27T02:00:19.245Z Has data issue: false hasContentIssue false
  • English
  • Français

Lithium Intercalation in Oxides: EMF Related to Structure and Chemistry

Published online by Cambridge University Press:  25 February 2011

K. West ,
B. Zachau-Christiansen ,
T. Jacobsen  and
S. Skaarup
K. West
Affiliation:
Department of Physical Chemistry and Physics Laboratory IIIThe Technical University of Denmark, DK–2800 Lyngby, Denmark.
B. Zachau-Christiansen
Affiliation:
Department of Physical Chemistry and Physics Laboratory IIIThe Technical University of Denmark, DK–2800 Lyngby, Denmark.
T. Jacobsen
Affiliation:
Department of Physical Chemistry and Physics Laboratory IIIThe Technical University of Denmark, DK–2800 Lyngby, Denmark.
S. Skaarup
Affiliation:
Physics Laboratory IIIThe Technical University of Denmark, DK–2800 Lyngby, Denmark.
Get access

Abstract

Experimental results for a number of oxide host materials as electrodes in lithium batteries are compared in order to obtain a better understanding of the factors influencing the emf-composition relationships. These factors are divided into two main groups: Those that are consequences of the structure of the host lattice, and those who follow from the chemistry of the host material. Series of materials with the same structure, but different chemical composition (spinels and MO2(B)) are compared, as well as series of materials with the same chemical composition, LixV2O5, but different structure. These data show that the potential level is mainly determined by the host chemistry, although destabilisation of the host can also give a significant contribution. The host structure will determine the width of the composition interval as well as the inflexions on the emf-curve. The possibility for tailoring the emf by using mixtures of transition metals in the host lattice is discussed.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 293: Symposium U – Solid State Ionics III , 1992 , 39
Copyright
Copyright © Materials Research Society 1993

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1. Steele, B.C.H. in Fast Ion Transport in Solids, edited by Gool, G. van (North Holland, 1973) 103.Google Scholar
2. Armand, M.B. in Fast Ion Transport in Solids, edited by Gool, G. van (North Holland, 1973) 685.Google Scholar
3. Murphy, D.W., Christian, P.A., Salvo, F.J. Di and Carides, J.N, J. Electrochem. Soc. 126, (1979) 497.Google Scholar
4. Murphy, D.W. and Christian, P.A., Science, N.Y. 205, (1979) 651.Google Scholar
5. Zachau-Christiansen, B., West, K., Jacobsen, T. and Atlung, S., Solid State Ionics 40/41, (1990) 580.Google Scholar
6. Thdobald, F., Cabala, R. and Bernard, J., J. Solid State Chem. 17 191 (1976).Google Scholar
7. Zachau-Christiansen, B., West, K., Jacobsen, T. and Skaarup, S., Solid State lonics 53–56, (1992) 364.Google Scholar
8. Zachau-Christiansen, B., West, K. and Jacobsen, T., Mat. Res. Bull. 20 485 (1985).Google Scholar
9. Eibschiitz, M., Murphy, D.W., Zahurak, S.M. and Christian, P.A., Solid State lonics 5, (1981) 339.Google Scholar
10. Eibschfutz, M., Murphy, D.W., Zahurak, S.M. and Christian, P.A., Appl. Phys. Lett. 39, (1981) 664.Google Scholar
11. Raistrick, I.D., Mark, A.J. and Huggins, R.A., Solid State lonics 5 351 (1981).Google Scholar
12. West, K., Zachau-Chrilstiansen, B., Skaarup, S. and Jacobsen, T., Solid State Ionics 53–56, (1992) 356.Google Scholar
13. Margalit, N., J. Electrochem. Soc. 121, (1974) 1461.Google Scholar
14. Tarascon, J.M, Wang, E., Shokoohi, F.K., McKinnon, W.R. and Colson, S., J. Electrochem. Soc. 138 (1991) 2859.Google Scholar
15. Zachau-Christiansen, B., West, K., Jacobsen, T. and Skaarup, S., to be published.Google Scholar
16. Galy, J., Darriet, J. and Hagenmuller, P., Rev. Chim. Minér. 8, (1971) 509.Google Scholar
17. Hagenmuller, P., Galy, J., Pouchard, M. and Casalot, A., Mat. Res. Bull. 1, (1966) 45.Google Scholar
18. West, K., in High Conductivity Solid Ionic Conductors, Recent Trends and Applications, edited by Takahashi, T. (World Scientific Publishing Company, Singapore, 1989) 447.Google Scholar
19. Liaw, B.Y., Raistrick, I.D. and Huggins, R.A., Solid State lonics 45, (1991) 323.Google Scholar
20. Cocciantelli, J.M., Doumerc, J.P., Pouchard, M., Broussely, M. and Labat, J., J. Power Sources 34, (1991) 103.Google Scholar
21. Cocciantelli, J.M., Gravereau, P., Doumerc, J.P., Pouchard, M. and Hagenmuller, P., J. Solid State Chem. 93, (1991) 497.Google Scholar
22. Delmas, C., Brèthes, S. and Menetrier, M., J. Power Sources 34, (1991) 113.Google Scholar
23. Picciotto, L.A. de, Thackeray, M.M., Dawid, W.I.F., Bruce, P.G. and Goodenough, J.B., Mat. Res. Bull. 19, (1984) 1497.Google Scholar
24. Mizushima, K., Jones, P.C., Wiseman, P.J., Goodenough, J.B., Mat. Res. Bull. 15, (1980) 783.Google Scholar
25. Gummow, R.J. and Thackeray, M.M., Solid State lonics 53–56, (1992) 681.Google Scholar