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Light-Controllable Chiral Photochromic Multifunctional Liquid Crystal Polymers

Published online by Cambridge University Press:  15 March 2011

Valery P. Shibaev ,
Alexey Yu. Bobrovsky  and
Natalia I. Boiko
Valery P. Shibaev
Affiliation:
Chemistry Department, Moscow State University Lenin Hills, 19899 Moscow, Russia
Alexey Yu. Bobrovsky
Affiliation:
Chemistry Department, Moscow State University Lenin Hills, 19899 Moscow, Russia
Natalia I. Boiko
Affiliation:
Chemistry Department, Moscow State University Lenin Hills, 19899 Moscow, Russia
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Abstract

A new family of light-controllable chiral photochromic multifunctional liquid crystalline (LC) side-chain acrylic polymers consisting of nematogenic, chiral and photochromic monomer units was obtained. The new principle of photoregulation of the helical supramolecular structure and optical properties of the binary and ternary chiral photochromic LC polymers based on the change of helical twisting power of the chiral photochromic monomer units was developed. The features of photooptical behaviour of LC polymers possessing the dual photochromism and the peculiarities of optical data recording based on the photochemical spectral gap burning were presented and discussed. The synthesized polymers are shown to be promising candidates for colour data recording and storage.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 709: Symposium CC – Advances in Liquid Crystalline Materials and Technologies , 2001 , CC4.4.1
Copyright
Copyright © Materials Research Society 2002

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References

REFERENCES

1. Shibaev, V.P., Bobrovsky, A.Yu., Boiko, N.I., Polym. Int. 49, 931 (2000)Google Scholar
2. Shibaev, V.P., Bobrovsky, A.Yu., Boiko, N.I., Polymer Science, Ser. C, 42, 2205 (2000)Google Scholar
3. Broer, D.J., Lub, J., Mol, G.N., Nature 378, 467 (1995)Google Scholar
4. Polymers as Electrooptical and Photooptical Active Media, Shibaev, V. (Ed.), Springer Verlag, Berlin-Heidelberg 1996 Google Scholar
5. Bobrovsky, A.Yu., Boiko, N.I., Shibaev, V.P., Polymer Science, Ser. A, 39, 528 (1997)Google Scholar
6. Bobrovsky, A.Yu., Boiko, N.I., Shibaev, V.P., Liq.Cryst., 24, 489 (1998)Google Scholar
7. Boiko, N.I., Thesis, Moscow State University, Moscow, 1987 Google Scholar
8. Bobrovsky, A.Yu., Boiko, N.I., Shibaev, V.P., Liq. Cryst. 27, 57 (2000)Google Scholar
9. Bobrovsky, A.Yu., Boiko, N.I., Shibaev, V.P., Adv. Materials. 12, 1180, (2000)Google Scholar
10. Bobrovsky, A.Yu., Boiko, N.I., Shibaev, V.P., Liq. Cryst. 26, 1749 (1999)Google Scholar
11. Shibaev, V.P., Kostromin, S.G., Ivanov, S.A., Polymer Science, Ser. A. 39, 118 (1997)Google Scholar
12. Shibaev, V.P., Intern.J.Polym. Mater. 45, 307 (2000)Google Scholar
13. Bobrovsky, A.Yu., Boiko, N.I., Shibaev, V.P., J. Mater.Chem., 10, 1075 (2000)Google Scholar
14. Bobrovsky, A.Yu., Boiko, N.I., Shibaev, V.P., J. Photochem.&Photobiol., 138, 261 (2001)Google Scholar
15. Bobrovsky, A.Yu., Boiko, N.I., Shibaev, V.P., Adv.Mater. 11, 1025 (1999)Google Scholar