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Laser Assisted Deposition of Carbon Nitride Coatings

Published online by Cambridge University Press:  10 February 2011

Ashok Kumar
Affiliation:
Advanced Thin Film Laboratory, Department of Electrical and Computer Engineering, EEB 60, University of South Alabama, Mobile, AL 36688;
R. Alexandrescu
Affiliation:
National Institute for Lasers, Plasma and Radiation Physics, P. 0. Box MG-36, R- 76900, Bucharest, Romania.
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Abstract

We have investigated the growth of carbon nitride (CNx) coatings on various substrates using laser assisted methods such as pulsed laser deposition (PLD) and laser chemical vapor deposition (LCVD). It has been shown that the both techniques produce good quality thin films of CNx. In PLD, a laser beam (λ= 248 nm) has been used to ablate the pyrolytic graphite target in nitrogen atmosphere, where as CO2 laser was used to irradiate carbon-nitrogen containing mixtures such as C2H2/N20/NH3 in LCVD method. A comparative analysis will be presented in terms of structural properties of CNx films prepared by both techniques.

Type
Research Article
Copyright
Copyright © Materials Research Society 1999

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References

1. Liu, A. Y. and Cohen, M. L., Science 245, 841 (1989)Google Scholar
2. Liu, A. Y. and Cohen, M. L., Phys. Rev. B 41, 10727 (1990)Google Scholar
3. Marton, D., Boyd, K. J., AI-Bayati, A. H., Todorov, S. S., and Rabalais, J. W., Phys. Rev. Lett. 73, 118 (1994)Google Scholar
4. Zhang, Y. F., Zhou, Z. H. and Li, H. L., Appl. Phys. Lett. 68, 634 (1996)Google Scholar
5. He, Xiao-Ming, Shu, Li, Li, Wen-Zhi, and Li, Heng-De, J. Mater. Res., 12 (6), 1595 (1997)Google Scholar
6. Bhusari, D. M., Chen, C. K., Chen, K. H., Chen, L. C., and Chuang, T. J., MRS Symp. Proc., 441,693 (1997)Google Scholar
7. Maya, L., Cole, D. R., and Hagaman, E. W., J. Am. Ceram. Soc. 74, 1686 (1991)Google Scholar
8. Wixom, M. R., J. Am. Ceram. Soc. 73, 1973 (1990)Google Scholar
9. Yu, K. M., Cohen, M. L., Haller, E. E., Hansen, W. L., Liu, A. Y. and Wu, I. C., Phys. Rev. B 49, 5043 (1994)Google Scholar
10. Niu, C., Lu, Y. Z. and Liber, C. M., Science 261, 334 (1993)Google Scholar
11. Kumar, Ashok, Ekanayake, U., Inturi, R. B. and Barnard, J. A.MRS symposium Proceeding, Vol.434, 189194 (1996)Google Scholar
12. Kumar, A. et. al., J of Materials Engineering and Performance, Vol.6 (5), 583 (1997)Google Scholar
13. Li, D., Wong, M. S., Chung, Y. W., Cheng, S. C., Chu, X., Lin, X. W., David, V., and Sproul, W. D., Appl. Phys. Lett. 67, 203 (1995)Google Scholar
14. Narayan, J., Tiwari, P., Xhen, X., et.al. Appl. Phys. Lett. 61, 1290 (1992)Google Scholar
15. Kumar, Ashok, Narayan, J., and Chen, X., Appl. Phys. Lett. 6, 976 (1992)Google Scholar
16. Alexandrescu, R., Cireasa, R., Punga, G., Crunteanu, A., Petcu, S., Morjan, I., Mihailescu, I. N., Andrie, A., Appl. Surf. Sci. 109110, 544 (1997)Google Scholar
17. Kjendal, D., M. S. Thesis, University of South Alabama (1995)Google Scholar
18. Alexandrescu, R., Cireasa, R., Cojocaru, C. S., Crunteanu, A., Morjan, I., Vasiliu, F. and Kumar, A., in Surface Modification Technologies XII, Edits. Sudarshan, T. S., Khor, K. A., Jeandin, M., ASM International Materials Park, Ohio (1998) to be publishedGoogle Scholar
19. Cireasa, R., Crunteanu, A., Alexandrescu, R., Morjan, I., Martin, C., Mihailescu, I. N., Andrei, A. and Vasiliu, F., Carbon, 36, vol.5–6, 775 (1998)Google Scholar
20. Mizokawa, Y., Miyasoto, T., Nakamura, S., Geib, K.M. and Wilmsen, C.W., J. Vac. Sci. Technolo. A 5, 2809 (1988)Google Scholar
21. Rossi, F., et al, J. Mater. Res., 9(9), 2440 (1994)Google Scholar
22. Hoffman, A., Gousman, I. and Brener, R., Appl. Phys. Lett. 64, 845 (1994)Google Scholar
23. Diani, M., et al, Dia. and Rel. Mat., 3, 264 (1994)Google Scholar
24. Guo, Y. and IIIGoddard, W. A., Chem. Phys. Lett. 237, 72 (1995)Google Scholar
25. Zhang, Y., Zhan, Z. and Li, H., Appl. Phys. Lett. 68, 634 (1996)Google Scholar
26. Li, D., Chung, Y. W., Wong, W. S. and Sproul, W. D., J. Appl. Phys. 74, 219 (1993)Google Scholar
27. Wu, Z., Yu, Y. and Liu, X., Appl. Phys. Lett. 68, 1291 (1996)Google Scholar
28. Morton, D., Boyd, K. I., Al-Bayati, A. H., Todorov, S. and Rabalais, J. W., Phys. Rev. Lett. 73, 118 (1994)Google Scholar
29. Crunteanu, A., Cireasa, R., Alexandrescu, R., Morjan, I., Nelea, V., Mihailescu, I. N. and Andrei, A., Surface and Coating Technology, 100–101, 173 (1998)Google Scholar