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A Kinetic Model for the Stability of the Spent Fuel Matrix Under Oxic Conditions: Model Development Against Experimental Evidence

Published online by Cambridge University Press:  03 September 2012

Jordi Bruno ,
E. Cera ,
L. Duro ,
T. E. Eriksen ,
P. Sellin ,
K. Spahiu  and
L. O. Werme
Jordi Bruno
Affiliation:
QuantiSci, Pare Tecnologie del Vallès, 08290 Cerdanyola del Vallès, Barcelona (Spain).
E. Cera
Affiliation:
QuantiSci, Pare Tecnologie del Vallès, 08290 Cerdanyola del Vallès, Barcelona (Spain).
L. Duro
Affiliation:
QuantiSci, Pare Tecnologie del Vallès, 08290 Cerdanyola del Vallès, Barcelona (Spain).
T. E. Eriksen
Affiliation:
Dept. of Nuclear Chemistry, Royal Institute of Technology, S 100 44, Stockholm (Sweden).
P. Sellin
Affiliation:
Swedish Nuclear Fuel and Waste Management (SKB), Box 5864, S 102 48, Stockholm (Sweden).
K. Spahiu
Affiliation:
Swedish Nuclear Fuel and Waste Management (SKB), Box 5864, S 102 48, Stockholm (Sweden).
L. O. Werme
Affiliation:
Swedish Nuclear Fuel and Waste Management (SKB), Box 5864, S 102 48, Stockholm (Sweden).
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Abstract

A kinetic model recently developed [1] for the radiolytically induced oxidative dissolution of the spent fuel matrix is presented. This is based on experimental studies on the generation and evolution of radiolytic products in a closed system containing fragments of PWR-fuel [2]. The outcome of this model is currently being integrated in the present PA exercise being prepared by SKB. The calibration of the model against various experimental information and its predictive capabilities for the long term performance of the spent fuel matrix are presented.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 465: Symposium II – Scienfific Basis for Nuclear Waste Management XX , 1996 , 491
Copyright
Copyright © Materials Research Society 1997

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References

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