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Ion-Beam-Synthesised Ag-SiO2 Nanocomposite Layers for Electron Field Emission Devices

Published online by Cambridge University Press:  26 February 2011

Wei-Mong Tsang
Affiliation:
[email protected], Advanced Technology Institute, School of Electronics and Physical Sciences, University of Surrey, Guildford, Surrey, GU2 7XH, United Kingdom, +44 01483 686088, +44 01483 689404
V. Stolojan
Affiliation:
Advanced Technology Institute, School of Electronics and Physical Sciences, University of Surrey, GU2 7XH, U.K.
A. A. D. T. Adikaari
Affiliation:
Advanced Technology Institute, School of Electronics and Physical Sciences, University of Surrey, GU2 7XH, U.K.
S. P. Wong
Affiliation:
Department of Electronic Engineering & Materials Science and Technology Research Centre, The Chinese University of Hong Kong, Hong Kong, China
S. R. P. Silva
Affiliation:
Advanced Technology Institute, School of Electronics and Physical Sciences, University of Surrey, GU2 7XH, U.K.
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Abstract

Ag-SiO2 nanocomposite layers were synthesised by Ag+ implantation into thermally oxidised SiO2 layers and demonstrated to have excellent field emission (FE) properties. These nanocomposite layers can give an emission current of 1 nA at electric fields less than 20 V/μm, compared to several thousand volts per micrometre of pure metal surfaces. Their fabrication processes are fully compatible with existing integrated circuit technology. By correlating the FE results with other characterisation techniques including atomic force microscopy, Rutherford backscattering spectroscopy and transmission electron microscopy, it is clearly demonstrated that there are two types of field enhancement mechanisms responsible for the excellent FE properties of these cathodes. Firstly, the electrically conductive Ag nano-clusters embedded in the insulating SiO2 matrix give rise to a local electric field enhancement due to an electrical inhomogeneity effect and secondly, the dense surface protrusions provide a geometric local electric field enhancement. The FE properties of these layers are critically dependent on the size and distribution of the Ag clusters, which can be controlled by the Ag dose and modified by the post-implantation pulse annealing with a high power KrF Excimer laser operating at 248 nm.

Type
Research Article
Copyright
Copyright © Materials Research Society 2006

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References

1 Zhu, W., Vacuum microelectronics, John Wiley & Sons, Inc (2001).Google Scholar
2 Funaki, Y, Mochizuki, Y, Flat panel market to 10 trillion yen by 2010. Mikkei Microdevices, Flat panel display yearbook, InterLingua, California USA, (1999), p. 75 Google Scholar
3 Gröning, O., Küttel, O.M., Gröning, P. and Schlaphach, L., Appl. Surf. Sci. 111, 135 (1996).Google Scholar
4 Ilie, A., Ferrari, A.C., Yagi, T., Robertson, J., Appl. Phys. Lett. 76, 2627 (2000).Google Scholar
5 Carey, J.D., Forrest, R.D., Khan, R.U.A., Silva, S.R.P., Appl. Phys. Lett. 77, 2006 (2000).Google Scholar
6 Tsang, W.M., Wong, S.P. and Lindner, J.K.N., Appl. Phys. Lett. 81, 3942 (2002).Google Scholar
7 Xu, N.S. and Huq, S. E., Mater. Sci. & Eng. R27, 47 (2005).Google Scholar
8 Cattaruzza, E., Nucl. Instr. and Meth. B 169, 141 (2000).Google Scholar
9 Battaglin, G., Nucl. Instr. and Meth. B 116, 102 (1996).Google Scholar
10 Weast, R. C., CRC Handbook of Chemistry and Physics, 81th ed., Chemical Rubber, Boca Raton, FL, (2000-2001)Google Scholar
11 Tsang, W.M., Stolojan, V., Wong, S. P., Sealy, B. J. and Silva, S. R. P., Mater. Sci. & Eng. B (in press).Google Scholar
12 Tsang, W. M., Wong, S. P. and Lindner, J. K. N., Appl. Phys. Lett. 84, 3193 (2004).Google Scholar
13 McBrayer, J.F., Swanson, R.M., Sigmon, T. W. and Bravman, J., Appl. Phys. Lett. 43, 653 (1983).Google Scholar
14 Gonella, F., Mattei, G., Mazzoldi, P., Cattaruzza, E., Arnold, G. W., Battaglin, G., Calvelli, P., Polloni, R., Bertoncello, R., and Haglund, R. F. Jr., Appl. Phys. Lett. 69, 3101 (1996).Google Scholar
15 Stepanov, A.L., Hole, D.E., Bukharaev, A.A., Townsend, P.D. and Hurgazizov, N.I., Appl. Surf. Sci. 136, 298 (1998).Google Scholar
16 Stepanov, A.L., Hole, D.E. and Townsend, P.D., Nucl. Instr. and Meth. B 149, 89 (1999).Google Scholar