Hostname: page-component-586b7cd67f-gb8f7 Total loading time: 0 Render date: 2024-11-23T08:34:37.109Z Has data issue: false hasContentIssue false
  • English
  • Français

Investigation of Mg2Si formation from Si and Mg by using spark plasma sintering synthesis

Published online by Cambridge University Press:  13 March 2015

Kota Sunohara ,
Koya Arai ,
Tomoyuki Nakamura ,
Kenjiro Fujimoto ,
Yuki Yamaguchi ,
Tsutomu Iida  and
Keishi Nishio
Kota Sunohara
Affiliation:
Department of Materials Science and Technology, Tokyo University of Science, 6-3-1 Niijyuku, Katsushika-ku, Tokyo 125-8585, Japan
Koya Arai
Affiliation:
Department of Materials Science and Technology, Tokyo University of Science, 6-3-1 Niijyuku, Katsushika-ku, Tokyo 125-8585, Japan
Tomoyuki Nakamura
Affiliation:
Department of Materials Science and Technology, Tokyo University of Science, 6-3-1 Niijyuku, Katsushika-ku, Tokyo 125-8585, Japan SWCC Showa Cable Systems Co., LTD. 4-1-1 Minami-Hashimoto Chuo-Ku Sagamihara, Kanagawa, Japan
Kenjiro Fujimoto
Affiliation:
Department of Pure and Applied Chemistry, Tokyo University of Science, 2641 Yamazaki, Noda-shi, Chiba 278-8510, Japan
Yuki Yamaguchi
Affiliation:
Department of Pure and Applied Chemistry, Tokyo University of Science, 2641 Yamazaki, Noda-shi, Chiba 278-8510, Japan
Tsutomu Iida
Affiliation:
Department of Materials Science and Technology, Tokyo University of Science, 6-3-1 Niijyuku, Katsushika-ku, Tokyo 125-8585, Japan
Keishi Nishio
Affiliation:
Department of Materials Science and Technology, Tokyo University of Science, 6-3-1 Niijyuku, Katsushika-ku, Tokyo 125-8585, Japan
Get access

Abstract

In this study, we fabricated Mg2Si from metal Mg and Si with different particle sizes (425 - 300, 300 - 180, and 75 μm or less) using spark plasma sintering (SPS) equipment. Additionally, the Mg2Si formation was investigated. A sieved Si powder was mixed with metal Mg powder in an inert gas (Ar) atmosphere. The mixture was placed in a graphite die while still in an Ar atmosphere and subjected to SPS at 923 K and 1113 K. The obtained sintering bodies were Mg2Si particles with a size of about 5 μm. Then, the sintered bodies were evaluated by X-ray diffraction (XRD). As a result, it was confirmed that generation of Mg2Si increased with decreasing Si particle size.

Keywords

thermoelectricMgSi
Type
Articles
Information
MRS Online Proceedings Library (OPL) , Volume 1735: Symposium S/W/CC – Advanced Materials for Photovoltaic, Fuel Cell and Electrolyzer, and Thermoelectric Energy Conversion , 2015 , mrsf14-1735-cc14-06
Copyright
Copyright © Materials Research Society 2015 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Heller, M. W. and Danielson, G. C., J. Phys. Chem. Solids 23, 601 (1962)CrossRefGoogle Scholar
LaBotz, R. J., Mason, D. R., and O’Kane, D. F., J. Electrochem. Soc. 110, 121 (1963)CrossRefGoogle Scholar
Noda, Y., Kon, H., Furukawa, Y., Otsuka, N., Nishida, I., and Matsumoto, K., Mater. Trans. JIM 33, 845 (1992)CrossRefGoogle Scholar
Tani, J. and Kido, H., Physica B 223, 364 (2005)Google Scholar
Zaitsev, V. K., Fedorv, M. I., Gurieva, E. A., Eremin, I. S., Konstantinov, P. P., Samunin, A. Yu., and Vedernikov, M. V., Phys. Rev. B74, 045207 (2006)CrossRefGoogle Scholar
Kajlkawa, T., Shida, K., Sugihara, S.. International Conference on Thermoelectrics Proc. 275–278 (1997)Google Scholar
JCPDS 340458(ICDD) Google Scholar
JCPDS 10714938(ICDD) Google Scholar
JCPDS 350821(ICDD) Google Scholar
JCPDS 261481(ICDD) Google Scholar