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Intra-Monolayer Hydrogen-Bonding in Monolayer Protected Gold Clusters

Published online by Cambridge University Press:  17 March 2011

Andrew K. Boal  and
Vincent M. Rotello
Andrew K. Boal
Affiliation:
Department of Chemistry University of Massachusetts, Amherst Amherst M.A. 01003
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Abstract

Unlike the highly ordered Self-Assembled Monolayers (SAMs) formed on flat gold surfaces, those on gold nanoparticles radiate from a roughly spherical center and are amorphous in structure. One result of this structural motif is that the strength of intra- monolayer non-covalent interactions, such as Φ-stacking and hydrogen bonding, are a function of the distance of the recognition element from the colloidal core. We present here an exploration of these phenomena in amide functionalized thiols in MPCs where the amide functionality position was varied in the alkane chain. [1]

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 635: Symposium C – Anisotropic Nanoparticles-Synthesis, Characterization & Applications , 2001 , C4.19
Copyright
Copyright © Materials Research Society 2001

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References

1. The majority of this work has appeared in print previously, see: Boal, A. K., Rotello, V. M., Langmuir 16, 9527 (2000).Google Scholar
2. (a) Bain, C. D., Troughton, E. B., Tao, Y.-T., Evall, J., Whitesides, G. M., Nuzzo, R. G., J. Am. Chem. Soc. 111, 321 (1989). (b) Ulman, A. An Introduction to Ultrathin Organic Films, (Academic Press, Boston, M. A., 1991).Google Scholar
3. Templeton, A. C., Wuelfing, W. P., Murray, R. W., R. W., Acc. Chem. Res. 33, 27 (2000).Google Scholar
4. (a) Luedtke, W. D., Landman, U., J. Phys.Chem. 100, 13323, (1996). (b) M. J. Hostetler, J. J. Stokes, R. W. Murray, Langmuir 12, 3604 (1996).Google Scholar
5. (a) Boal, A. K., Rotello, V. M., J. Am. Chem. Soc. 121, 4914 (1999). (b) A. K. Boal, V. M. Rotello, J. Am. Chem. Soc. 122, 734 (2000).Google Scholar
6. Brust, M., Walker, M., Bethell, D., Schiffrin, D. J., Whyman, R., Chem. Comm. 801 (1994).Google Scholar
7. Clegg, R. S., Hutchison, J. E. Langmuir 12,5239 (1996).Google Scholar
8. Tam-Chang, S.-W., Biebuych, H. A., Whitesides, G. M., Jeon, N., Nuzzo, R. G., Langmuir 11,4371 (1995).Google Scholar
9. Badia, A., Singh, S., Demers, L., Cuccia, L., Brown, G. R., Lennox, R. B., Chem. Eur. J. 2,359 (1996).Google Scholar