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Interfacial layer bonding and Dielectric properties of Hf-O-N gate dielectric thin films

Published online by Cambridge University Press:  01 February 2011

Karthik Ramani
Affiliation:
[email protected], University of Florida, Singh Research Group, Materials Science and Engineering, ., FL, ., United States, 352-392-5714, 352-846-0326
Chad Robert Essary
Affiliation:
[email protected], University of Florida, Gainesville, FL, 32611, United States
Valentin Craciun
Affiliation:
[email protected], University of Florida, Gainesville, FL, 32611, United States
Rajiv K Singh
Affiliation:
[email protected], University of Florida, Gainesville, FL, 32611, United States
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Abstract

The electrical response and interfacial layer characterization of nitrogen doped HfO2 gate dielectric thin films are reported. The films were processed at relatively low temperature (~ 400 0C) by pulsed laser deposition and ultra-violet radiation assisted oxidation technique. Nitrogen incorporation in the hafnia films led to O-N and Hf-Si-O-N bonding in the bulk and at hafnia-Si interface respectively. The nitrogen doped hafnia films exhibited a leakage current density lower than 10E-5 A/sq cm at -1 V and a simulated equivalent oxide thickness of 9.4 Å.

Type
Research Article
Copyright
Copyright © Materials Research Society 2006

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References

1 Gusev, E. P., Cabral, C., Copel, M., D'Emic, C., and Gribelyuk, M., Microelectronic Engineering 69, 145151 (2003).Google Scholar
2 Balog, M., Schieber, M., Michman, M., and Patai, S., Thin Solid Films 41, 247259 (1977).Google Scholar
3 Balog, M., Schieber, M., Michman, M., and Patai, S., Journal of Crystal Growth 17, 298-& (1972).Google Scholar
4 Kirsch, P. D., Kang, C. S., Lozano, J., Lee, J. C., and Ekerdt, J. G., Journal of Applied Physics 91, 43534363 (2002).Google Scholar
5 Visokay, M. R., Chambers, J. J., Rotondaro, A. L. P., Shanware, A., and Colombo, L., Applied Physics Letters 80, 31833185 (2002).Google Scholar
6 Ekerdt, J. G. and Kirsch, P. D., Abstracts of Papers of the American Chemical Society 221, U368–U368 (2001).Google Scholar
7 Choi, C. H., Jeon, T. S., Clark, R., and Kwong, D. L., IEEE Electron Device Letters 24, 215217 (2003).Google Scholar
8 Luo, Q., Dragomir-Cernatescu, I., Snyder, R. L., Rees, W. S., and Hess, D. W., Journal of the Electrochemical Society 153, F1–F7 (2006).Google Scholar
9 Akbar, M. S., Gopalan, S., Cho, H. J., Onishi, K., Choi, R., Nieh, R., Kang, C. S., Kim, Y. H., Han, J., Krishnan, S., and Lee, J. C., Applied Physics Letters 82, 17571759 (2003).Google Scholar
10 Singh, D., Kim, W. S., Craciun, V., Hofmann, H., and Singh, R. K., Applied Surface Science 197, 516521 (2002).Google Scholar
11 Srivastava, A., Craciun, V., Howard, J. M., and Singh, R. K., Applied Physics Letters 75, 30023004 (1999).Google Scholar
12 Yang, H. S., Choi, J., Song, S. J., and Singh, R. K., Electrochemical and Solid State Letters 7, C4–C6 (2004).Google Scholar
13 Yang, H. S., Choi, J. Y., Craciun, V., and Singh, R. K., Journal of Applied Physics 93, 78737875 (2003).Google Scholar
14 Baulch, D. L., Cox, R. A., Hampson, R. F., Kerr, J. A., Troe, J., and Watson, R. T., Journal of Physical and Chemical Reference Data 9, 295471 (1980).Google Scholar
15 Moulder, J. F., Stickle, W. F., Sobol, P. E., and Bomben, K. D., Handbook of X-ray photoelectron spectroscopy (Physical Electronics. Inc.).Google Scholar
16 Wagner, C. D., Passoja, D. E., Hillery, H. F., Kinisky, T. G., Six, H. A., Jansen, W. T., and Taylor, J. A., Journal of Vacuum Science & Technology 21, 933944 (1982).Google Scholar
17 Kang, C. S., Cho, H. J., Onishi, K., Nieh, R., Choi, R., Gopalan, S., Krishnan, S., Han, J. H., and Lee, J. C., Applied Physics Letters 81, 25932595 (2002).Google Scholar
18 Kim, J., Kim, S., Kang, H., Choi, J., Jeon, H., Cho, M., Chung, K., Back, S., Yoo, K., and Bae, C., Journal of Applied Physics 98, - (2005).Google Scholar
19 Hauser, J., CVC (NCSU) Version 3.0 (1996).Google Scholar
20 Punchaipetch, P., Okamoto, T., Nakamura, H., Uraoka, Y., Fuyuki, T., and Horii, S., Japanese Journal of Applied Physics Part 1-Regular Papers Short Notes & Review Papers 43, 78157820 (2004).Google Scholar
21 Brar, B., Wilk, G. D., and Seabaugh, A. C., Applied Physics Letters 69, 27282730 (1996).Google Scholar
22 Eason, K., Jallepally, R., Noble, D., Hattangady, S., Khamankar, R., and Rotondaro, A. L. P., Proc.- Electrochem. Soc. 2000-9 (2001).Google Scholar