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Interface Effect on Dipole-Dipole Interaction

Published online by Cambridge University Press:  15 February 2011

Michael Urbakh
Affiliation:
School of Chemistry, Tel-Aviv University, Tel Aviv 69978, Israel
Joseph Klafter
Affiliation:
School of Chemistry, Tel-Aviv University, Tel Aviv 69978, Israel
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Abstract

The nature of the pair interaction between dipoles embedded in a liquid in the vicinity of a non-metallic interface is investigated in the continuum limit. It is shown that the dipole-dipole interaction can be significantly modified in the presence of a boundary in liquids characterized by a nonlocal dielectric function or in liquids whose dielectric properties change due to geometrical restrictions. Different limits are studied and relationships to experimental observables are discussed.

Type
Research Article
Copyright
Copyright © Materials Research Society 1993

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References

1. Klafter, J. and Drake, J.M., Eds. Molecular Dynamics in Restricted Geometries, (John Wiley, New York, 1989).Google Scholar
2. Drake, J.M., Klafter, J. and Kopelman, R., Eds. Dynamics in Small Confining Systems, (MRS,Pittsburgh, 1990).Google Scholar
3. Evans, R., J. Phys.: Condens. Matt. 2, 8989 (1990).Google Scholar
4. Awschalom, D.D. and Wamnock, J., In ref 1.Google Scholar
5. Watanabe, M., Brodsky, A.M., and Reinhardt, W.P., J. Phys. Chem. 95, 4593 (1991).Google Scholar
6. Vorotyntsev, M.A., and Komyshev, A.A., Soy. Phys. JETP 51, 509 (1980).Google Scholar
7. Vorotyntsev, M.A., in Advances of Science and Engineering, Electrochemistry, 26, 3 (1988) (in Russian).Google Scholar
8. Drake, J.M. and Klafter, J., Physics Today 43, 46 (1990).Google Scholar
9. Urbakh, M., and Klafter, J., J. Phys. Chem. 96, 3480 (1992).Google Scholar
10. Agranovich, V.M., and Ginzburg, V.L., Spatial Dispersion in Crystal Optics and the Theory of Excitons, (Interscience, New York, 1976).Google Scholar
11. See, e.g.: The Chemical Physics of Solvation, edited by Dogonadze, R.R., Kalman, E., Komyshev, A.A. and Ulstrup, J.., (Elsevier, Amsterdam, 1988), Parts A and C.Google Scholar
12. Nee, Tsu-Wei and Zwanzig, R., J. Chem. Phys. 52, 6353 (1970).Google Scholar
13. S.Alavi, D. and Waldeck, D.H. J. Chem. Phys. 94, 6196 (1991).Google Scholar
14. Enderby, J.E. and Neilson, G.W., Rep. Progr. Phys. 44, 953 (1981).Google Scholar
15. Pollock, E.L. and Alder, B.J., Phys. Rev. Lett. 46, 950 (1981).Google Scholar
16. Revere, M., Miniero, R., Parinello, M. and Tosi, M.P., Phys. Chem. Liq. 9, 11 (1979).Google Scholar
17. Israelachvili, J.N., Intermolecular and Surface Forces with Applications to Colloidal and Biological Systems, (Academic Press, London, 1985).Google Scholar
18. (a) Davis, H.T., Somers, S.A., Tirrell, M. and Bitsanis, I., in Danamics in Small Confining Systems, Extended Abstract of 1990 Fall Meeting of the MRS, edited by Drake, J.M., Klafter, J. and Kopelman, R., p 73. (b) M. Lupkowski, and F. van Swol, In Dynamics in Small Confining Systems, Extended Abstract of 1990 Fall Meeting of the MRS, edited by J.M. Drake, J. Klafter and R. Kopelman, p 19.Google Scholar
19. Vorotyntsev, M.A., in The Chemical Physics of Solvation, edited by Dogonadze, R.R., Kalman, E., Kornyshev, A.A. and Ulstrup, J., (Elsevier, Amsterdam, 198)8, Part C, p 401.Google Scholar
20. Harrison, W., Solid State Theory, (McGraw-Hill, New York, 1970).Google Scholar
21. Abramovitz, M., and Stegun, I., Eds., Handbook of Mathematical Functions, (Dover, New York, 1965).Google Scholar
22. Komyshev, A.A., Rubinstein, A.I. and Vorotyntsev, M.A., J. Phys. C. Solid State Phys. 11, 3307 (1978).Google Scholar
23. Kornyshev, A.A. and Leikin, S., Phys. Rev. B40, 6431 (1989); M.K. Granfeldt and Bo Jonsson, Chem. Phys. Lett. 195, 174 (1992).Google Scholar
24. Kornyshev, A.A., J. Electroanal. Chem. 255, 297 (1988).Google Scholar
25. Agranovich, V.M. and Galanin, M.D., Electronic Excitation Energy Transfer in Condenced Matter, (North-Holland, Amsterdam, 1982).Google Scholar
26. Levitz, P., Drake, J.M. and Klafter, J., J. Chem. Phys. 89, 5224 (1988).Google Scholar
27. Manne, S.,Hasma, P.K., Massie, J., Elings, V.B. and Gewirth, A.A., Science 251, 133 (1991).Google Scholar
28. Goodman, F. and Garcia, N., Phys. Rev. B43, 4728 (1991).Google Scholar
29. Garcia, N. and Binh, Vu Thien, Phys. Rev. B46, 7946 (1992).Google Scholar
30. Rand, R.P. and Parsegian, V.A., Biochim. Biophys. Acta, 988, 351 (1990).Google Scholar
31. Cevc, G. and Kornyshev, A., J. Electroanal. Chem., 330, 407 (1992)Google Scholar