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The Interaction of Na-Al-P-Glass (Cs, Sr-Bearing) with Water at Elevated Temperatures (70–250°C)

Published online by Cambridge University Press:  15 February 2011

Alexander P. Mukhamet-Galeyev ,
Larisa O. Magazina ,
Konstantin A. Levin ,
Nikolay D. Samotoin ,
Alexander V. Zotov  and
Boris I. Omelianenko
Alexander P. Mukhamet-Galeyev
Affiliation:
Institute of Geology of Ore Deposits, Petrography, Mineralogy and Geochemistry, Russian Academy of Sciences, Staromonetny 35, 109017 Moscow, Russia
Larisa O. Magazina
Affiliation:
Institute of Geology of Ore Deposits, Petrography, Mineralogy and Geochemistry, Russian Academy of Sciences, Staromonetny 35, 109017 Moscow, Russia
Konstantin A. Levin
Affiliation:
Institute of Geology of Ore Deposits, Petrography, Mineralogy and Geochemistry, Russian Academy of Sciences, Staromonetny 35, 109017 Moscow, Russia
Nikolay D. Samotoin
Affiliation:
Institute of Geology of Ore Deposits, Petrography, Mineralogy and Geochemistry, Russian Academy of Sciences, Staromonetny 35, 109017 Moscow, Russia
Alexander V. Zotov
Affiliation:
Institute of Geology of Ore Deposits, Petrography, Mineralogy and Geochemistry, Russian Academy of Sciences, Staromonetny 35, 109017 Moscow, Russia
Boris I. Omelianenko
Affiliation:
Institute of Geology of Ore Deposits, Petrography, Mineralogy and Geochemistry, Russian Academy of Sciences, Staromonetny 35, 109017 Moscow, Russia
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Extract

At present Na-Al-P-glass is used in Russia as matrix for high level nuclear waste which include a sufficient portion of 90Sr and 137Cs isotopes. It has been known that this type of glass is characterized by relatively poor hydrothermal stability above 120°C (Krilova et al., 1990 [1], Balukova et al., 1987 [2]). Although careful studies were devoted to the glass, some questions of geochemical behavior of Sr and Cs in the limits of the nearest repository environment have remained undecided. For example, these have been left uncertain: the mechanism of the glass leaching, phenomena limiting the glass dissolution, the detailed composition of newly formed phases, temperature dependence of the glass solubility. The main purpose of the present experimental investigation was to detect factors controlling Sr and Cs concentrations of aquous solutions and to study the possibility of new solid phase formation as a factor slowing down migration of Cs and Sr in water satureted circumstance.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 353: Symposium – Scientific Basis for Nuclear Waste Management XVIII , 1994 , 79
Copyright
Copyright © Materials Research Society 1995

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References

REFERENCES

1. Balukova, V.D., Savushkina, R.N. The assessment of the solid radioactive waste leaching processes in the presence of water and barrier materials. Atomnaya Energiya, 1987, v.63, N 4, p.277–279.Google Scholar
2. Krilova, N.V., Salamatina, R.N., Shavruk, V.V. et al. The study of possible component leaching from phosphate glasses by granite formation water. Atomnaya Energiya, 1990, v. 69, N 5, p.303–306.Google Scholar
3. Lasaga, A.C. Rate laws of chemical reactions. In Kinetics of Geochemical Processes eds Lasaga, A.C. & Kirkpatrick, R.J., Miner. Soc. Amer., 1981, p. 35.Google Scholar
4. Bates, J.K., Steindler, M.J. Alteration on nuclear waste glass by hydration. Mat. Res. Soc Proc., 1983, v 15, 83–90.Google Scholar