Hostname: page-component-586b7cd67f-t7czq Total loading time: 0 Render date: 2024-11-26T15:34:40.276Z Has data issue: false hasContentIssue false
  • English
  • Français

In-situ preparation of metal oxide thin films by inkjet printing acetates solutions

Published online by Cambridge University Press:  11 July 2013

Mei Fang ,
Wolfgang Voit ,
Yan Wu ,
Lyubov Belova  and
K.V. Rao
Mei Fang
Affiliation:
Department of Physics, Fudan University, Shanghai 200433, China Department of Materials Science and Engineering, KTH-Royal Institute of Technology, Stockholm, SE10044, Sweden
Wolfgang Voit
Affiliation:
Department of Materials Science and Engineering, KTH-Royal Institute of Technology, Stockholm, SE10044, Sweden
Yan Wu
Affiliation:
Faculty of Materials Science and Chemical Engineering, China University of Geosciences, Wuhan, 430074, China
Lyubov Belova
Affiliation:
Department of Materials Science and Engineering, KTH-Royal Institute of Technology, Stockholm, SE10044, Sweden
K.V. Rao
Affiliation:
Department of Materials Science and Engineering, KTH-Royal Institute of Technology, Stockholm, SE10044, Sweden
Get access

Abstract

Direct printing of functional oxide thin films could provide a new route to low-cost, efficient and scalable fabrications of electronic devices. One challenge that remains open is to design the inks with long term stability for effective deposition of specific oxide materials of industrial importance. In this paper, we introduce a reliable method of producing stable inks for ‘in-situ’ deposition of oxide thin films by inkjet printing. The inks were prepared from metal-acetates solutions and printed on a variety of substrates. The acetate precursors were decomposed into oxide films during the subsequent calcination process to achieve the ‘in-situ’ deposition of the desired oxide films directly on the substrate. By this procedure we have obtained room temperature contamination free ferromagnetic spintronic materials like Fe doped MgO and ZnO films from their acetate(s) solutions. We find that the origin of magnetism in ZnO, MgO and their Fe-doped films to be intrinsic. For a 28 nm thick film of Fe-doped ZnO we observe an enhanced magnetic moment of 16.0 emu/cm3 while it is 5.5 emu/cm3 for the doped MgO film of single pass printed. The origin of magnetism is attributed to cat-ion vacancies. We have also fabricated highly transparent indium tin oxide films with a transparency >95% both in the visible and IR range which is rather unique compared to films grown by any other technique. The films have a nano-porous structure, an added bonus from inkjetting that makes such films advantageous for a broad range of applications.

Keywords

ink-jet printingoxidethin film
Type
Articles
Information
MRS Online Proceedings Library (OPL) , Volume 1547: Symposium M – Solution Synthesis of Inorganic Functional Materials—Films, Nanoparticles and Nanocomposites , 2013 , pp. 13 - 20
Copyright
Copyright © Materials Research Society 2013 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

Sirringhaus, H., Kawase, T., Friend, R. H., Shimoda, T., Inbasekaran, M., Wu, W., and Woo, E. P., Science 290, 2123 (2000).CrossRefGoogle Scholar
Kawase, T., Shimoda, T., Newsome, C., Sirringhaus, H., and Friend, R. H., Thin Solid Films 438-439, 279 (2003).CrossRefGoogle Scholar
Stutzmann, N., Friend, R. H., and Sirringhaus, H., Science 299, 1881 (2003).CrossRefGoogle Scholar
Sekitani, T., Noguchi, Y., Zschieschang, U., Klauk, H., and Someya, T., Proceedings of the National Academy of Sciences of the United States of America 105, 4976 (2008).CrossRefGoogle Scholar
Yan, H., Chen, Z., Zheng, Y., Newman, C., Quinn, J. R., Dötz, F., Kastler, M., and Facchetti, A., Nature 457, 679 (2009).CrossRefGoogle Scholar
Shimoda, T., Morii, K., Seki, S., and Kiguchi, H., MRS Bulletin 28, 821 (2003).CrossRefGoogle Scholar
Huang, D., Liao, F., Molesa, S., Redinger, D., and Subramanian, V., Journal of the Electrochemical Society 150, G412 (2003).CrossRefGoogle Scholar
Lee, H. H., Chou, K. S., and Huang, K. C., Nanotechnology 16, 2436 (2005).CrossRefGoogle Scholar
Tobjörk, D. and Österbacka, R., Advanced Materials 23, 1935 (2011).CrossRefGoogle Scholar
Roth, E. A., Xu, T., Das, M., Gregory, C., Hickman, J. J., and Boland, T., Biomaterials 25, 3707 (2004).CrossRefGoogle Scholar
Hoth, C. N., Schilinsky, P., Choulis, S. A., and Brabec, C. J., Nano Letters 8, 2806 (2008).CrossRefGoogle Scholar
Eom, S. H., Senthilarasu, S., Uthirakumar, P., Yoon, S. C., Lim, J., Lee, C., Lim, H. S., Lee, J., and Lee, S. H., Organic Electronics: physics, materials, applications 10, 536 (2009).CrossRefGoogle Scholar
Xu, T., Jin, J., Gregory, C., Hickman, J. J., and Boland, T., Biomaterials 26, 93 (2005).CrossRefGoogle Scholar
Barbulovic-Nad, I., Lucente, M., Sun, Y., Zhang, M., Wheeler, A. R., and Bussmann, M., Critical Reviews in Biotechnology 26, 237 (2006).CrossRefGoogle Scholar
Calvert, P., Chemistry of Materials 13, 3299 (2001).CrossRefGoogle Scholar
Singh, M., Haverinen, H. M., Dhagat, P., and Jabbour, G. E., Advanced Materials 22, 673 (2010).CrossRefGoogle Scholar
Magdassi, S., The chemistry of inkjet inks (World Science Publising Co. Pte. Ltd., Singapore, 2010).Google Scholar
Kim, G. H., Kim, H. S., Shin, H. S., Ahn, B. D., Kim, K. H., and Kim, H. J., Thin Solid Films 517, 4007 (2009).CrossRefGoogle Scholar
Huang, C.-C., Su, P.-C., and Liao, Y.-C., Thin Solid Films.Google Scholar
Fan, J., Boettcher, S. W., and Stucky, G. D., Chemistry of Materials 18, 6391 (2006).CrossRefGoogle Scholar
Boettcher, S. W., Fan, J., Tsung, C. K., Shi, Q., and Stucky, G. D., Accounts of Chemical Research 40, 784 (2007).CrossRefGoogle Scholar
Fan, J., Dai, Y., Li, Y., Zheng, N., Guo, J., Yan, X., and Stucky, G. D., Journal of the American Chemical Society 131, 15568 (2009).CrossRefGoogle Scholar
Liu, X., et al. ., Nano Letters 12, 5733 (2012).CrossRefGoogle Scholar
Fang, M., Voit, W., Kyndiah, A., Wu, Y., Belova, L., and Rao, K., MRS Proceedings 1394 (2012).CrossRefGoogle Scholar
Girgis, E., Fang, M., Hassan, E., Kathab, N., and Rao, K. V., Journal of Materials Research 28, 502 (2012).CrossRefGoogle Scholar
Wu, Y., Zhan, Y., Fahlman, M., Fang, M., Rao, K., and Belova, L., MRS Proceedings 1292 (2011).CrossRefGoogle Scholar
Lin, Y., Jiang, D., Lin, F., Shi, W., and Ma, X., Journal of Alloys and Compounds 436, 30 (2007).CrossRefGoogle Scholar
Kapilashrami, M., Xu, J., Ström, V., Rao, K. V., and Belova, L., Applied Physics Letters 95 (2009).CrossRefGoogle Scholar
Hong, N. H., Chikoidze, E., and Dumont, Y., Physica B: Condensed Matter 404, 3978 (2009).CrossRefGoogle Scholar
Araujo, C. M., et al. ., Applied Physics Letters 96 (2010).CrossRefGoogle Scholar
Kim, H.-K., You, I.-K., Koo, J. B., and Kim, S.-H., Surface and Coatings Technology 211, 33 (2012).CrossRefGoogle Scholar
Hwang, M.-s., Jeong, B.-y., Moon, J., Chun, S.-K., and Kim, J., Materials Science and Engineering: B 176, 1128 (2011).CrossRefGoogle Scholar
Jeong, J.-A. and Kim, H.-K., Current Applied Physics 10, e105 (2010).CrossRefGoogle Scholar