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Initial Phase Formation and Distribution in the Pt-GexSi1−x and Cr-GexSi1−x Systems
Published online by Cambridge University Press: 25 February 2011
Abstract
Metal-GeSi reactions have been investigated in the Pt-GeSi and Cr-GeSi systems. Pt started to diffuse into and react with the alloys at 250 °C. The reacted region consisted of a uniform mixture of Pt2Si and Pt2Ge, with the same ratios of Ge to Si as those in the unreacted region. On the other hand, the Cr-GeSi reaction was induced by Ge motion at 375 °C. As a result a two-layer phase separation was observed. A Si-rich ternary layer was sandwiched between a germanide layer and the unreacted alloy
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