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Infrared Characterization of PMMA-SiO2 Hybrid Glasses Obtained by Sol-Gel Process

Published online by Cambridge University Press:  01 February 2011

L.L. Díaz-Flores ,
A. S. López Rodríguez ,
P. SifuentesGallardo ,
M.A. Hernàndez Rivera ,
M.a Garnica Romo ,
R. Bernal  and
J.M. Yáñez-Limón
L.L. Díaz-Flores
Affiliation:
Universidad Juárez Autónoma de Tabasco, Av. Universidad S/N Zona de la Cultura CP. 86000 Villahermosa, Tabasco, México
A. S. López Rodríguez
Affiliation:
Universidad Juárez Autónoma de Tabasco, Av. Universidad S/N Zona de la Cultura CP. 86000 Villahermosa, Tabasco, México
P. SifuentesGallardo
Affiliation:
Universidad Juárez Autónoma de Tabasco, Av. Universidad S/N Zona de la Cultura CP. 86000 Villahermosa, Tabasco, México
M.A. Hernàndez Rivera
Affiliation:
Universidad Juárez Autónoma de Tabasco, Av. Universidad S/N Zona de la Cultura CP. 86000 Villahermosa, Tabasco, México
M.a Garnica Romo
Affiliation:
Facultad de Ingeniería Mecánica Universidad Michoacana de San Nicolás de Hidalgo Santiago Tapia 403, Col. Centro, CP 58000, Morelia, Michoacán, México
R. Bernal
Affiliation:
Departamento de Investigación en Física, Universidad de Sonora, Apdo. Postal 5-088, Hermosillo, Sonora 83190, México Email: [email protected]
J.M. Yáñez-Limón
Affiliation:
CINVESTAV-QRO Libramiento Norponiente 2000, Fracc. Real de Juriquilla, CP 76820 Querétaro, Qro, México
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Abstract

This work is about the production of hybrid coatings of the system SiO2-PMMA (PMMA, polymethylmethacrylate). These materials have interesting mechanical and chemical properties useful for anticorrosive and wear resistance applications. SiO2-PMMA hybrids were obtained by the sol-gel traditional process, using tetraethylorthosilicate (TEOS) and methylmethacrylate (MMA) by Aldrich Co, as starting reagents. The SiO2:PMMA ratio was varied from 0:1 to about 1:1 at air atmosphere deposition. The coatings were obtained on acrylic sheets and silicon wafers. A diversity of coatings with chemical composition ranging from SiO2 and PMMA to obtain the SiO2-PMMA hybrids were obtained. Infrared (IR) and atomic force microscopy (AFM), were performed to determinate structural and morphological behavior.

Keywords

Hybrid materialsSol-gelPMMAFilms
Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 1278: Composite, Hybrid Materials and Ecomaterials , 2010 , S08-13
Copyright
Copyright © Materials Research Society 2010

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References

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