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The Influence of Plasma Excitation Frequency on the Properties of a-SiC:H Produced in a Glow Discharge Plasma

Published online by Cambridge University Press:  28 February 2011

W. D. Partlow  and
H. Herzig
W. D. Partlow
Affiliation:
Westinghouse R&D Center, Pittsburgh, PA 15235 NASA Goddard Space Flight Center, Greenbelt, MD 20771
H. Herzig
Affiliation:
Westinghouse R&D Center, Pittsburgh, PA 15235 NASA Goddard Space Flight Center, Greenbelt, MD 20771
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Abstract

We have deposited a-SiC:H thin films from a silane-methane glow discharge plasma in a planar reactor using high (13Mhz and low (12kHz) frequency plasma excitation. Films produced at these two frequencies have significantly different properties as measured by vacuum UV reflectivity measurements, XPS, and infrared spectroscopy. Samples produced at the low excitation frequencies, where higher ion fluxes and energies are expected, have higher VUV reflectivities, higher bulk plasmon energies, and fewer IR bands due to organic fragments. In order to relate the VUV reflectivity data to the material properties, it was fitted to a simple Lorentz model using parameters taken from XPS data. We will discussour interpretation of these data and also the dependence of film properties on the reactant gas composition.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 49: Symposium F – Materials Issues in Applications of Amorphous Silicon Technology , 1985 , 181
Copyright
Copyright © Materials Research Society 1985

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References

1. Catherine, Y. and Turban, G., Thin Solid Films 60, 193 (1979).CrossRefGoogle Scholar
2. Roedern, B. von, Mahan, A. H., Williamson, D. L., and Madan, A., Proceedings of the 5th Symposium on Materials and New Processint Technologies for Photovoltaics, New Orleans, LA October, 1984.Google Scholar
3. Catherine, Y., Zamouche, A., Bullot, J., and Gauthier, M., Thin Solid Films 109 14 (1983).CrossRefGoogle Scholar
4. Rehn, Victor and Choyke, W. J., Nuclear Instruments and Methods 177, 173 (1980).CrossRefGoogle Scholar
5. Hozso, F., Muelhoff, L., Trenary, M., Choyke, W. J., and Yates, J. T., J. Vac. Sci. Technol. (in press).Google Scholar
6. Thornton, J. A., Ann. Rev. Mat. Sci. 7, 239 (1977).CrossRefGoogle Scholar
7. Ross, R. C. and Messier, R., J. Appl. Phys. 52, 6329 (1981).Google Scholar
8. Wooton, Frederick, “Optical Properties of Solids, Academic Press, New York (1972).Google Scholar
9. Choyke, W. J., Private communication.Google Scholar