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Influence of Macrocyclic Ligands on Ion Transport in Solid Polyelectrolytes

Published online by Cambridge University Press:  28 February 2011

K. Chen
Affiliation:
Northwestern University, Department of Chemistry and Materials Research Center, Evanston, IL 60208
K. Doan
Affiliation:
Northwestern University, Department of Chemistry and Materials Research Center, Evanston, IL 60208
S. Ganapathiappan
Affiliation:
Northwestern University, Department of Chemistry and Materials Research Center, Evanston, IL 60208
M. Ratner
Affiliation:
Northwestern University, Department of Chemistry and Materials Research Center, Evanston, IL 60208
D. F. Shriver
Affiliation:
Northwestern University, Department of Chemistry and Materials Research Center, Evanston, IL 60208
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Abstract

Cryptands and crown ethers increase the cation transport in phosphazene and alkoxyaluminate polyelectrolytes. Vibrational spectroscopy indicates that the increased conductivity originates from reduced ion pairing.

Type
Research Article
Copyright
Copyright © Materials Research Society 1991

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References

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