Hostname: page-component-586b7cd67f-t7fkt Total loading time: 0 Render date: 2024-11-23T07:19:47.191Z Has data issue: false hasContentIssue false

Improvement in Diffusion Length Estimation using the Photocurrent-Capacitance Method in CuInSe2-based Cells

Published online by Cambridge University Press:  21 March 2011

Clifford H. Champness*
Affiliation:
Electrical and Computer Engineering Department, McGill University, 3480 University Street, Montreal, Quebec, Canada, H3A 2A7
Get access

Abstract

The experimental technique in the photocurrent-capacitance method of estimating minority diffusion lengths, as applied to CuInSe2-based photovoltaic cells, has been improved, principally by replacing the earlier chopped light and monochromator technique by one employing a steady strong stable light source and a long pass optical filter. The filter requires an absorption edge at an appropriate wavelength to provide the penetrating light at sufficient intensity, which has been found to be 1.1 μm for CuInSe2 cells and 1.0 μ for Cu(In,Ga)Se2 cells. In addition, the parallel capacitance is determined with reverse bias under the same illumination as that during the photocurrent measurements and at a suitable frequency, such as 10 kHz. With these changes, the technique has been found to be more tolerant to cell imperfections and reproducible estimates of diffusion length have been obtained on CuInSe2 and Cu(In,Ga)Se2 cells.

Type
Research Article
Copyright
Copyright © Materials Research Society 2001

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Smith, K.L. and Abbot, M., Solid State Electronics 15, 361 (1972).Google Scholar
2. Young, M.L. and Rowland, M.C., Phys. Status Solidi A 16, 603 (1973).Google Scholar
3. Dorantes-Davila, J., Lastras-Martinez, A. and Raccah, P.M., Appl. Phys. Lett. 38, 442 (1981).Google Scholar
4. Tygai, V.A., Soviet Phys. Solid State 6, 1260 (1964), translated from Fizika Tverdogo Tela 6, 1602, No. 6 (1984).Google Scholar
5. Lastras-Martinez, A., Raccah, P.M. and Triboulet, R., Appl. Phys. Lett. 36, 469 (1980).Google Scholar
6. Shukri, Z.A. and Champness, C.H., NREL/SNL Photovoltaics Program Review (A.I.P. Press, New York, 1997), p.603.Google Scholar
7. Al-Quraini, A.A. and Champness, C.H., Proc. 26th IEEE Photovoltaic Specialists Conf. (1997), p.415.Google Scholar
8. Yip, L.S. and Shih, I., 1st World Conf. on Photovoltaic Energy Conversion 2, 210 (1994).Google Scholar
9. Lam, W.W. and Shih, I., Materials Letters 33, 69 (1999).Google Scholar
10. Champness, C.H., Proc. 16th European Photovoltaic Solar Energy Conf. (2000), pp. 698701.Google Scholar