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Homoepitaxial Growth of Crystalline Ge Films through a Liquid Metal Medium at Low Temperature

Published online by Cambridge University Press:  25 February 2011

Fulin Xiong
Affiliation:
Gordon McKay Laboratory of Applied Science, Harvard University, Cambridge, MA 02138
Jene A. Golovehenko
Affiliation:
Gordon McKay Laboratory of Applied Science, Harvard University, Cambridge, MA 02138
Frans Spaepen
Affiliation:
Gordon McKay Laboratory of Applied Science, Harvard University, Cambridge, MA 02138
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Abstract

Crystalline films of Ge have been homoepitaxially grown through a liquid Au medium by the so-called vapor-liquid-solid (VLS) mechanism at relatively low temperature (400-450 °C). During the process, the Ge vapor is delivered by a molecular beam evaporator and the liquid phase in the system is formed at the interface by heating a Au metal film above its eutectic point with the semiconductor. This process has a potential of a high growth rate at low temperature. The growth process and the crystallinity of the films were monitored in situ by high energy ion backscattering and channeling. The surface morphology and quality of the films were examined by scanning electron microscopy and cross-sectional transmission electron microscopy. The experimental results are presented, together with a discussion of the growth mechanism and the nature of the liquid metal-semiconductor interface.

Type
Research Article
Copyright
Copyright © Materials Research Society 1991

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References

REFERENCES

1. Wagner, R. S. and Ellis, W. C., Appl. Phys. Lett. 4, 89 (1964).Google Scholar
2. Wagner, R. S. and Ellis, W. C., Trans. of the Metallug. Soc. of AIMS, 233, 1053 (1965).Google Scholar
3. Lau, S. S. and Weg, W. F. van der, Solid Phase Epitaxy, in Thin films - Reactions and Diffusions, eds. Poate, J. M., Tu, K. N., and Mayer, J. W. (John Wiley, New York, 1978).Google Scholar
4. Lau, S. S., Mayer, J. W., and Tseng, W., Solid Phase Epitaxial Growth of Si and Ge, in Handbook on Semiconductors, Vol. 3. Materials, Properties and Preparation, ed. Keller, S. (North-Holland, Amsterdam, 1980); and references therein.Google Scholar
5. Allen, L. H., Phillips, J. R., Thedore, D., Carter, C. B., Soave, R., Mayer, J. W., and Ottaviani, G., Phys. Rev. B 41, 8203 (1990).Google Scholar
6. Allen, L. H., Mayer, J. W., Tu, K. N., and Feldman, L. C., Phys. Rev. B 41, 8213 (1990).Google Scholar
7. Binarary Alloy Phase Diagrams, eds. Murray, J. L., Bennett, L. H., and Baker, H. (American Society for Metals, 1986).Google Scholar
8. Narusawa, T., Kinoshita, K., and Gibson, W. M., J. Vac. Sci. Technol. 18, 872 (1981).Google Scholar