Hostname: page-component-7bb8b95d7b-l4ctd Total loading time: 0 Render date: 2024-10-02T14:55:09.678Z Has data issue: false hasContentIssue false

High-Surface - Area Framework Zirconium Phosphates as Catalysts of Hexane Isomerization and Dehydroaromatization: Synthesis and Properties

Published online by Cambridge University Press:  15 February 2011

Vladislav A. Sadykov
Affiliation:
Boreskov Institute of Catalysis, Siberian Branch of the RAS, Lavrentieva, 5, Novosibirsk, RUSSIA; 630090, [email protected]
S. N. Pavlova
Affiliation:
Boreskov Institute of Catalysis, Siberian Branch of the RAS, Lavrentieva, 5, Novosibirsk, RUSSIA; 630090, [email protected]
G. V. Zabolotnaya
Affiliation:
Boreskov Institute of Catalysis, Siberian Branch of the RAS, Lavrentieva, 5, Novosibirsk, RUSSIA; 630090, [email protected]
D. I. Kochubey
Affiliation:
Boreskov Institute of Catalysis, Siberian Branch of the RAS, Lavrentieva, 5, Novosibirsk, RUSSIA; 630090, [email protected]
R. I. Maximovskaya
Affiliation:
Boreskov Institute of Catalysis, Siberian Branch of the RAS, Lavrentieva, 5, Novosibirsk, RUSSIA; 630090, [email protected]
V. I. Zaikovskii
Affiliation:
Boreskov Institute of Catalysis, Siberian Branch of the RAS, Lavrentieva, 5, Novosibirsk, RUSSIA; 630090, [email protected]
V. V. Kriventsov
Affiliation:
Boreskov Institute of Catalysis, Siberian Branch of the RAS, Lavrentieva, 5, Novosibirsk, RUSSIA; 630090, [email protected]
S. V. Tsybulya
Affiliation:
Boreskov Institute of Catalysis, Siberian Branch of the RAS, Lavrentieva, 5, Novosibirsk, RUSSIA; 630090, [email protected]
E. B. Burgina
Affiliation:
Boreskov Institute of Catalysis, Siberian Branch of the RAS, Lavrentieva, 5, Novosibirsk, RUSSIA; 630090, [email protected]
E. A. Paukshtis
Affiliation:
Boreskov Institute of Catalysis, Siberian Branch of the RAS, Lavrentieva, 5, Novosibirsk, RUSSIA; 630090, [email protected]
A. M. Volodin
Affiliation:
Boreskov Institute of Catalysis, Siberian Branch of the RAS, Lavrentieva, 5, Novosibirsk, RUSSIA; 630090, [email protected]
V. B. Fenelonov
Affiliation:
Boreskov Institute of Catalysis, Siberian Branch of the RAS, Lavrentieva, 5, Novosibirsk, RUSSIA; 630090, [email protected]
N. N. Kuznetsova
Affiliation:
Chemical Department, Lomonosov Moscow State Univ., Vorobyoby gory, Moscow, RUSSIA; 119899
V. V. Lunin
Affiliation:
Chemical Department, Lomonosov Moscow State Univ., Vorobyoby gory, Moscow, RUSSIA; 119899
M. V. Chaikina
Affiliation:
Institute of Solid State Chemistry, Siberian Branch of the RAS, Kutateladze, 18, Novosibirsk, RUSSIA, 630128
Dinesh Agrawal
Affiliation:
Materials Research Laboratory, The Pennsylvania State University, University Park, PA 16802
Rustum Roy
Affiliation:
Materials Research Laboratory, The Pennsylvania State University, University Park, PA 16802
Get access

Abstract

Mechanochemical activation of solid inorganic precursors and sol-gel routes followed by hydrothermal treatment in the presence of surfactants were used to synthesize highly dispersed NZP-type complex zirconium phosphates. Genesis of samples real structure and its impact on the surface properties and catalytic performance in the reactions of hexane isomerization and dehydroaromatization have been studied.

Type
Research Article
Copyright
Copyright © Materials Research Society 1999

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1. Goodenough, J.B., Hong, H. J., and Kafalas, J. A., Mater. Res. Bull. 11, 173 (1976).Google Scholar
2. Komarneni, S., Int. J. High Technol. Ceram. 4, 31 (1988).Google Scholar
3. Ciesla, U., Schacht, S., Stucky, G. D., Unger, K. K., and Schtith, F., Angew. Chem. Int. Ed. Engl. 35, 541 (1996).Google Scholar
4. Chaikina, M. V.., Chemistry for Sustainable Development 6, 141 (1998) (in Russian).Google Scholar
5. Bolshov, V. A., Volodin, A. M., Zhidomirov, G. M., Shubin, A. A., and Bedilo, A. F., J. Phys. Chem. 98, 7551 (1994).Google Scholar
6. Ono, A., and Okamura, F., Bull. Chem. Soc. Jpn. 58, 1051 (1985).Google Scholar
7. Pavlova, S. N., Sadykov, V. A., Paukshtis, E. A., Burgina, E. B., Degtyarev, S. P., Kochubei, D. I., Saputina, N. F., Kalinkin, A. V., Maximovskaya, R. I., Zaikovskii, V. I., Roy, R. and Agrawal, D., Stud. Surf. Sci. Catal. 119, 759 (1998).Google Scholar