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Highly dispersed metal-clusters and -colloids for the preparation of active liquid-phase hydrogenation-catalysts

Published online by Cambridge University Press:  15 February 2011

Helmut Bönnemann ,
Werner Brijoux ,
Rainer Brinkmann ,
Eckard Dinjus ,
Rainer Fretzen ,
Thomas Joußen  and
Barbara Korall
Helmut Bönnemann
Affiliation:
Max-Planck-lnstitut für Kohlenforschung, Postfach 10 13 53, W-4330 Mülheim an der Ruhr, BRD
Werner Brijoux
Affiliation:
Max-Planck-lnstitut für Kohlenforschung, Postfach 10 13 53, W-4330 Mülheim an der Ruhr, BRD
Rainer Brinkmann
Affiliation:
Max-Planck-lnstitut für Kohlenforschung, Postfach 10 13 53, W-4330 Mülheim an der Ruhr, BRD
Eckard Dinjus
Affiliation:
Max-Planck-lnstitut für Kohlenforschung, Postfach 10 13 53, W-4330 Mülheim an der Ruhr, BRD
Rainer Fretzen
Affiliation:
Max-Planck-lnstitut für Kohlenforschung, Postfach 10 13 53, W-4330 Mülheim an der Ruhr, BRD
Thomas Joußen
Affiliation:
Max-Planck-lnstitut für Kohlenforschung, Postfach 10 13 53, W-4330 Mülheim an der Ruhr, BRD
Barbara Korall
Affiliation:
Max-Planck-lnstitut für Kohlenforschung, Postfach 10 13 53, W-4330 Mülheim an der Ruhr, BRD
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Summary

A comparison of the activities of conventionally precipitated metals on charcoal, deposited organometallic clusters and metal colloids for liquid-phase hydrogenation has been made under standard conditions in order to assess the effect of particle size. The strong SMSI-effect known for TiO2-supports was simulated on charcoal by doping the surface with small amounts of Ti(0) and subsequent oxygenation.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 272: Symposium O – Chemical Processes in Inorganic Materials: Metal and Semiconductor Clusters , 1992 , 67
Copyright
Copyright © Materials Research Society 1992

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References

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