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High Crystalline Quality Perovskite Thin Films Prepared by a Novel Hybrid Evaporation/CVD Technique

Published online by Cambridge University Press:  29 May 2015

Yanke Peng ,
Gaoshan Jing  and
Tianhong Cui
Yanke Peng
Affiliation:
State Key Laboratory of Precision Measurement Technology and Instruments, Department of Precision Instruments, Tsinghua University, Beijing, 100084, China
Gaoshan Jing
Affiliation:
State Key Laboratory of Precision Measurement Technology and Instruments, Department of Precision Instruments, Tsinghua University, Beijing, 100084, China
Tianhong Cui
Affiliation:
State Key Laboratory of Precision Measurement Technology and Instruments, Department of Precision Instruments, Tsinghua University, Beijing, 100084, China Department of Mechanical Engineering, University of Minnesota, Minneapolis, Minnesota 55455, USA
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Abstract

Performance of a perovskite based solar cell is highly determined by the crystalline qualities of the perovskite thin film sandwiched between an electron and a hole transport layer, such as grain size and uniformity of the film. Here, we demonstrated a new hybrid physical-chemical vapor deposition (HPCVD) technique to synthesis high quality perovskite films. First, a PbI2 precursor film was spin-coated on a mesoporous TiO2 (m-TiO2)/compact TiO2 (c-TiO2)/FTO substrate in ambient environment. Then, purified CH3NH3I crystal material was evaporated and the vapor reacted with the PbI2 precursor film in a vacuum pressure/temperature accurately controlled quartz tube furnace. In this technique, high vacuum (2mTorr) and low temperature (100°C) were applied to decrease perovskite film growth rate and reduce perovskite film defects. After vapor reaction, the perovskite film was annealed at 100°C for 10min in 20mTorr vacuum to recrystallize and remove CH3NH3I residue in order to further improve crystal quality of the thin film. Crystal quality of this perovskite thin film was characterized by scanning electron microscopy (SEM), atomic force microscopy (AFM), and X-ray diffraction (XRD). SEM and AFM results illustrate perovskite thin films synthesized by this technique have larger grain sizes and more uniformity (RMS 11.6nm/Ra 9.3nm) superior to most existing methods. Strong peaks shown in the XRD chart at 14.18°, 28.52°, 31.96°, which were assigned to (110), (220), (330) miller indices of CH3NH3PbI3 perovskite crystal, indicate the complete reaction between CH3NH3I vapor and PbI2 precursor layer. High power conversion efficiency (PCE) up to 12.3% and stable efficiencies under four hours illumination of AM1.5 standard were achieved by these solar cells. This vacuum/vapor based technique is compatible with conventional semiconductor fabrication techniques and high quality perovskite film could be achieved through delicate process control. Eventually, perovskite based solar cells could be mass produced in low cost for large scale applications by this novel technique.

Keywords

chemical vapor deposition (CVD) (chemical reaction)physical vapor deposition (PVD)grain size
Type
Articles
Information
MRS Online Proceedings Library (OPL) , Volume 1771: Symposium B/C/D/E – Recent Advances in Photovoltaics , 2015 , pp. 187 - 192
Copyright
Copyright © Materials Research Society 2015 

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References

REFERENCES

Kojima, A.; Teshima, K.; Shirai, Y.; Miyasaka, T. Journal of the American Chemical Society 2009, 131, (17), 6050–6051.CrossRefGoogle Scholar
http://www.nrel.gov/ncpv/images/efficiency_chart.jpg. (02–04),Google Scholar
Burschka, J.; Pellet, N.; Moon, S. J.; Humphry-Baker, R.; Gao, P.; Nazeeruddin, M. K.; Gratzel, M. Nature 2013, 499, (7458), 316–9.CrossRefGoogle Scholar
Jeon, N. J.; Noh, J. H.; Kim, Y. C.; Yang, W. S.; Ryu, S.; Seok, S. I. Nature materials 2014, 13, (9), 897–903.CrossRefGoogle Scholar
Huang, F.; Dkhissi, Y.; Huang, W.; Xiao, M.; Benesperi, I.; Rubanov, S.; Zhu, Y.; Lin, X.; Jiang, L.; Zhou, Y.; Gray-Weale, A.; Etheridge, J.; McNeill, C. R.; Caruso, R. A.; Bach, U.; Spiccia, L.; Cheng, Y.-B. Nano Energy 2014, 10, 10–18.CrossRefGoogle Scholar
Zhou, H.; Chen, Q.; Li, G.; Luo, S.; Song, T. B.; Duan, H. S.; Hong, Z.; You, J.; Liu, Y.; Yang, Y. Science 2014, 345, (6196), 542–6.CrossRefGoogle Scholar
Liu, M.; Johnston, M. B.; Snaith, H. J. Nature 2013, 501, (7467), 395–8.CrossRefGoogle Scholar
Chen, Q.; Zhou, H.; Hong, Z.; Luo, S.; Duan, H. S.; Wang, H. H.; Liu, Y.; Li, G.; Yang, Y. J Am Chem Soc 2014, 136, (2), 622–5.CrossRefGoogle Scholar
Luo, P.; Liu, Z.; Xia, W.; Yuan, C.; Cheng, J.; Lu, Y. ACS applied materials & interfaces 2015, 7, (4), 2708–14.CrossRefGoogle Scholar
Ha, S. T.; Liu, X. F.; Zhang, Q.; Giovanni, D.; Sum, T. C.; Xiong, Q. H. Advanced Optical Materials 2014, 2, (9), 838–844.CrossRefGoogle Scholar
Leyden, M. R.; Ono, L. K.; Raga, S. R.; Kato, Y.; Wang, S.; Qi, Y. J. Mater. Chem. A 2014.Google Scholar
Chen, Q.; Zhou, H.; Song, T. B.; Luo, S.; Hong, Z.; Duan, H. S.; Dou, L.; Liu, Y.; Yang, Y. Nano letters 2014, 14, (7), 4158–63.CrossRefGoogle Scholar