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Heat resistant polymer electrolyte for enhanced organic electrochromic windows based on poly (3,3-dimethyl-3,4-dihydro-2H-thieno[3,4-b][1,4]dioxepine)

Published online by Cambridge University Press:  09 June 2014

Nishita Anandan ,
Sooyeun Kim  and
Minoru Taya
Nishita Anandan
Affiliation:
University of Washington, Seattle
Sooyeun Kim
Affiliation:
University of Washington, Seattle
Minoru Taya
Affiliation:
University of Washington, Seattle
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Abstract

Electrochromic Windows(ECWs) have the potential to save energy through dynamic control of light and solar energy entering a room (via solar heat gain coefficient control). ECWs have been developed as an optical shutter in airplane, building and automobile applications. An ECW is composed of three components, a working electrode based on electrochromic materials, a counter electrode based on ion storage materials and the electrolyte as an ionic conducting layer. Organic ECWs have been gaining popularity due to easy and cost effective manufacturing, availability of wide range of colors, high optical contrast and flexibility in design. However there are challenges in commercialization and application of organic ECWs. The application of ECWs as a sunroof in automobiles demands operation in harsh environment conditions like elevated temperature. Consequently the University of Washington, Center for Intelligent Materials and Systems has been developing a heat resistant organic ECW that can be operated at elevated temperatures maintaining high optical contrast, fast switching speed, optical color memory and electrochemical stability. The proposed design is an ECW based on poly (3,3-dimethyl-3,4-dihydro-2H-thieno[3,4-b][1,4]dioxepine),PPRODOT-Me2 as a working electrode, V2O5-TiO2 composite materials as a counter electrode and poly(ethylene imine) based electrolyte. The ionic conductivity of the electrolyte was calculated through complex impedance method and temperature dependence of the electrolyte was determined using environment test chamber to control a temperature range of 15 to 80o Celsius for 100 hours. A 76 × 76 mm2 ECW was developed and the optical transmittance change was observed by Chronoamperomerty and Time course measurement. The electrochemical stability of the window was monitored using cyclic voltammetry. The developed electrochromic window showed good optical contrast, electrochemical stability and fast response time after testing at elevated temperatures for 100 hours.

Keywords

optoelectronicenvironmentally protectivepolymer
Type
Articles
Information
MRS Online Proceedings Library (OPL) , Volume 1695: Symposium FF – The Grand Challenges in Organic Electronics , 2014 , mrss14-1695-ff04-47
Copyright
Copyright © Materials Research Society 2014 

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References

REFERENCE

Stephan, A.M, Eur. Polym J. 42(1), 21–42(2006)CrossRefGoogle Scholar
Benedict, T.J., Banumathi, S., Veluchamy, A., Gangadharan, R.. Ahamad, A.Z and Rajendran, S., J. Power Sources , 75(1), 171–4(1998)CrossRefGoogle Scholar
Ito, Y., Kanehori, K., Miyauchi, k., Kudo, T., J. Mater. Sci , 22(5), 1845–1849(1987)CrossRefGoogle Scholar
Nagasubramanian, G. and Distefano, S., J. Electrochem, Soc. 137(12), 3830–3835(1990)CrossRefGoogle Scholar
Abraham, K.M and Alamgir, M., J. Electrochem. Soc. 1990, 137(5), 1657–1658(1990)CrossRefGoogle Scholar
Appetecchi, G.B. and Scrosati, B., Electrochim Acta , 43(9), 1105–1107(1998)CrossRefGoogle Scholar
Choe, H.S., Carroll, B.G., Pasquariello, D.M. and Abraham, K.M., J. Electrochem. Soc , 142(6), 369–379(1997)Google Scholar
Vondrak, J., Reiter, J., Velicka, J., Klapste, B., Sedlarikova, M., Dvorak, J., J. Power Sources , 146(1), 436–440(2005)CrossRefGoogle Scholar
Vondrak, J., Reiter, J., Velicka, J., Sedlarikova, M., Solid State Ionics , 170(1-2), 79–82(2005)CrossRefGoogle Scholar
Mohamed, N. S and Arof, A.K, Phys Status Solidi A , 201(4), 3096–101(2004); J. Power Sources, 132(1-2), 229-234(2004) CrossRefGoogle Scholar
Jiang, Z., Carroll, B., Abraham, K.M., Electrochim Acta , 42(17), 2667–2677(1997)CrossRefGoogle Scholar
Unal, B., Klein, R.J., Yocca, K.R. and Hedden, R.C., Polymer , 48, 6077–6085(2007)CrossRefGoogle Scholar
Takahashi, T., Chiang, C.K, Davis, G.T. and Harding, C.A., Solid State Ionics , 18, 300–305(1986)Google Scholar
Kim, S.Y. and Taya, M., Solar energy materials and solar cells , 107, 225–229(2012); Electrochimica Acta, 55, 5307-5311(2010) CrossRefGoogle Scholar
Fontenot, C.J., Wiench, J.W., Pruski, M. and Schrader, G.L., Journal of Physical Chemistry B , 104, 11622–11631(2000)CrossRefGoogle Scholar
Limmer, S.J., Seraji, S., Wu, Y., Chou, T.P., Nguyu, C. and Cao, G.Z., Advanced Functional Materials , 12, 59–64(2002)3.0.CO;2-B>CrossRefGoogle Scholar