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Published online by Cambridge University Press: 26 February 2011
In the growth of GaAs and GaP from TMG strong differences are observed. Although the shape of the Arrhenius plot of the growth rate is similar, at low deposition temperatures the GaP growth rate is lower than that of GaAs. Additionally, more carbon is incorporated into GaP than into GaAs. Mass spectrometric studies on methyl desorption show that As has a stronger ability to aid the breaking of the final Ga-carbon bond than P.