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Group 12 Thiolates: Syntheses, Characterization and Decomposition Pathways

Published online by Cambridge University Press:  22 February 2011

Gertrud KrÄuter ,
Virgil L. Goedken ,
Bernhard NeumÜller  and
W. S. Rees Jr.
Gertrud KrÄuter
Affiliation:
Department of Chemistry and Materials Research and Technology Center, The Florida State University, Tallahassee, FL 32306-3006
Virgil L. Goedken
Affiliation:
Department of Chemistry and Materials Research and Technology Center, The Florida State University, Tallahassee, FL 32306-3006
Bernhard NeumÜller
Affiliation:
Department of Chemistry and Materials Research and Technology Center, The Florida State University, Tallahassee, FL 32306-3006
W. S. Rees Jr.
Affiliation:
Department of Chemistry and Materials Research and Technology Center, The Florida State University, Tallahassee, FL 32306-3006
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Abstract

Zinc- and cadmium bis(alkylthiolate) compounds have been prepared and converted into the appropriate binary metal sulfides by thermal treatment. Several mercury chlorothiolates have been synthesized and characterized by single crystal X-ray diffraction. Their decomposition pathways are discussed. The prepared binary metal sulfides have been studied by XRPD and - in selected cases - by particle size determination. The volatile co-products have been isolated and characterized by GC/MS.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 327: Symposium N – Covalent Ceramics II: Non-Oxides , 1993 , 35
Copyright
Copyright © Materials Research Society 1994

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