Hostname: page-component-cd9895bd7-jn8rn Total loading time: 0 Render date: 2024-12-27T01:57:33.287Z Has data issue: false hasContentIssue false
  • English
  • Français

Green Synthesis of Platinum-encapsulated Nickel Nanocatalyst and Its Microstructure Evaluation

Published online by Cambridge University Press:  31 January 2011

Iliana Medina-Ramirez ,
Xu-Bin Pan ,
Sajid Bashir  and
Jingbo Louise Liu
Iliana Medina-Ramirez
Affiliation:
[email protected], Universidad Autonoma de Aguascalientes, Chemistry, Aguascalientes, Mexico
Xu-Bin Pan
Affiliation:
[email protected], Texas A&M University-Kingsville, Environmental Engineering, Kingsville, Texas, United States
Sajid Bashir
Affiliation:
[email protected], Texas A & M University-Kingsville, Chemistry, Kingsville, Texas, United States
Jingbo Louise Liu
Affiliation:
[email protected]@gmail.com, Texas A & M University-Kingsville, Chemistry, Kingsville, Texas, United States
Get access

Abstract

Platinum (Pt) is the most efficient and highly utilized electrocatalsyt; however its high cost hinders its widespread use as a stand-alone catalyst. To remedy this problem, a nickel (Ni) encapsulated by Pt (NiⓔPt) nanocatalyst was fabricated using a cost-effective green colloidal method. The NiⓔPt nanoparticles (NPs) were then characterized using transmission electron microscope (TEM) equipped with X-ray energy dispersive spectroscopy (EDS), and X-ray powder diffraction (XRD) to determine the particle size distribution, morphology, elemental composition, and crystalline phase structure. The surface energetic was also measured using ZetaPALS™ to identify the stability of the colloidal suspension.

Keywords

nanostructuresurface chemistrykinetics
Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 1213: Symposium T – Nanomaterials for Polymer Electrolyte Membrane Fuel Cells , 2009 , 1213-T10-12
Copyright
Copyright © Materials Research Society 2010

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1 Gasteiger, H. A., Panels, J. E. and Yan, S. G., J Power Sources 127, 162 (2004).Google Scholar
2 Raghuveer, V., Manthiram, A., and Bard, A. J., J. Phys. Chem. B 109, 22909 (2005).Google Scholar
3 Zhang, L., Zhang, J., Wilkinson, D. P., and Wang, H., J Power Sources 156, 171 (2006).Google Scholar
4 Wee, J. H., Lee, K. Y. and Kim, S. H., J Power Sources 165, 667 (2007).Google Scholar
5 Zhang, J., Liu, Z., Han, B., Liu, D., Chen, J., He, J., and Jiang, T., Chemistry, A European Journal 10, 3531 (2004).Google Scholar
6 Zhang, F., Jin, R., Chen, J., Shao, C., Gao, W., Li, L., and Guan, N., Journal of Catalysis 232, 424 (2005).Google Scholar
7 Liu, J., Birss, V., and Hill, J., J AIChE Early View (DOI: 10.1002/aic.12080, 2009).Google Scholar
8 Smoluchowsky, M. von, Ann. Phys. (Leipzig) 48 1103 (1915).Google Scholar
9 Barreiro, L.A., Campanha, J.R. and Lagos, R.E., Physica A 283, 160 (2000) (see also arXiv: cond-mat/9910405).Google Scholar