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Graphene Metrology Using Fluorescence Quenching of Different Fluorescent Dyes

Published online by Cambridge University Press:  22 August 2012

Hamed Hosseini Bay ,
Maziar Ghazinejad ,
Miroslav Penchev ,
Isaac Ruiz ,
Zafer Mutlu ,
Mihrimah Ozkan  and
Cengiz S. Ozkan
Hamed Hosseini Bay
Affiliation:
Mechanical Engineering Department, University of California, 900 University Ave., Riverside, CA 92521, U.S.A.
Maziar Ghazinejad
Affiliation:
Mechanical Engineering Department, University of California, 900 University Ave., Riverside, CA 92521, U.S.A.
Miroslav Penchev
Affiliation:
Electrical Engineering Department, University of California, 900 University Ave., Riverside, CA 92521, U.S.A.
Isaac Ruiz
Affiliation:
Electrical Engineering Department, University of California, 900 University Ave., Riverside, CA 92521, U.S.A.
Zafer Mutlu
Affiliation:
Materials Science and Engineering Program, University of California, 900 University Ave., Riverside, CA 92521, U.S.A.
Mihrimah Ozkan
Affiliation:
Electrical Engineering Department, University of California, 900 University Ave., Riverside, CA 92521, U.S.A.
Cengiz S. Ozkan
Affiliation:
Mechanical Engineering Department, University of California, 900 University Ave., Riverside, CA 92521, U.S.A.
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Abstract

The unique structure and properties of graphene initiated broad fundamental and technological research, and highlighted graphene as a new candidate for various applications such as energy storage, solar cells and electronic devices. Chemical vapor deposition (CVD) has been utilized for industrial large-scale synthesis of graphene. Regardless of the synthesis process, graphene should be transferred to arbitrary substrates for different applications. The transfer processes, introduce defects such as wrinkles and cracks in graphene which compromise the properties and applications. In recent years, fundamental research has been focused on characterization of graphene to develop new techniques for large-scale, high-resolution graphene metrology. Herein, a complementary high throughput metrology technique using fluorescent quenching is further investigated for different fluorescent dyes to characterize CVD synthesized graphene.

Keywords

chemical vapor deposition (CVD) (deposition)optical propertiesdefects
Type
Articles
Information
MRS Online Proceedings Library (OPL) , Volume 1451: Symposium DD/EE – Nanocarbon Materials and Devices , 2012 , pp. 51 - 56
Copyright
Copyright © Materials Research Society 2012

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References

REFERENCES

Geim, A. K., Novoselov, K. S., “The rise of graphene”, nature materials, Vol. 6, 183–191 (2007).CrossRefGoogle ScholarPubMed
Castro Neto, A. H., Guinea, F., Peres, N. M. R., Novoselov, K. S., Geim, A. K., “The electronic properties of graphene”, Rev. Mod. Phys., Vol. 81, No.1, 109–161 (2009).CrossRefGoogle Scholar
Mattevi, C., Kim, H., Chhuwalla, M., “A review of chemical vapour deposition of graphene on copper”, J. Mater. Chem., 21, 3324–3334 (2011).CrossRefGoogle Scholar
Nair, R. R., Blake, P., Grigorenko, A. N., Novoselov, K. S., Booth, T. J., Stauber, T., Peres, N. M. R., Geim, A. K., “Fine Structure Constant Defines Visual Transparency of Graphene”, Science, 320, 1308 (2008).CrossRefGoogle ScholarPubMed
Kyle, J. R., Ozkan, C. S., Ozkan, M., “Industrial graphene metrology”, Nanoscale, 4, 3807–3819 (2012).CrossRefGoogle ScholarPubMed
Treossi, E., Melucci, M., Liscio, A., Gazzano, M., Samori, P., Palermo, V., “High-Contrast Visualization of Graphene Oxide on Dye-Sensitized Glass, Quartz, and Silicon by Fluorescence Quenching”, J. Am. Chem. Soc., 131, 15576–15577 (2009).CrossRefGoogle ScholarPubMed
Kim, J., Cote, L. J., Kim, F., Huang, J., “Visualizing Graphene Based Sheets by Fluorescence Quenching Microscopy”, J. Am. Chem. Soc., 132, 260–267 (2009).CrossRefGoogle Scholar
Kyle, J. R., Guvenc, A., Wang, W., Ghazinejad, M., Lin, J., Guo, S., Ozkan, C. S., Ozkan, M., “Centimeter-Scale High-Resolution Metrology of Entire CVD-Grown Graphene Sheets”, Small, Vol. 7, No.18, 2599–2606 (2011).CrossRefGoogle ScholarPubMed
Ramakrishna Matte, H. S. S., Subrahmanyam, K. S., Venkata Rao, K., George, S. J., Rao, C. N. R., “Quenching of fluorescence of aromatic molecules by graphene due to electron transfer”, Chemical Physics Letters, 506, 260–264 (2011).CrossRefGoogle Scholar
8.Swathi, R. S., Sebastian, K. L., “Resonance energy transfer from a dye molecule to graphene”, J. Chem. Phys. 129, 054703 (2008).CrossRefGoogle Scholar
Swathi, R. S., Sebastian, K. L., “Distance dependence of fluorescence resonance energy transfer”, J. Chem. Sci., 121, 777–787 (2009).CrossRefGoogle Scholar
Swathi, R. S., Sebastian, K. L., “Long range resonance energy transfer from a dye molecule to graphene has (distance)-4 dependence”, J. Chem. Phys., 130, 086101 (2009).CrossRefGoogle ScholarPubMed
Bondarev, S. L., Knyokshto, V. N., Stepuro, V. I, Stupak, A. P., Turban, A. A., “Fluorescence and Electronic Structure of the Laser Dye DCM in Solution and in Polymethylmethacrylate”, J. of Applied Spectroscopy, Vol. 71, No.2, 194–201 (2004).CrossRefGoogle Scholar
Liu, Y., Liu, C., Liu, Y., “Investigation on fluorescence quenching of dyes by graphite oxide and graphene”, Applied Surface Science, 257, 5513–5518 (2011).CrossRefGoogle Scholar
Urano, Y, Kamia, M., Kanda, K., Ueno, T., Hirose, K., Nagano, T., “Evolution of Fluorescein as a Platform for Finely Tunable Fluorescence Probes”, J. Am. Chem. Soc., 127, 4888–4894 (2005).CrossRefGoogle ScholarPubMed