Hostname: page-component-cd9895bd7-hc48f Total loading time: 0 Render date: 2024-12-27T01:34:17.420Z Has data issue: false hasContentIssue false

Grain Growth in Titanium Silicide Films During the Formation Reaction

Published online by Cambridge University Press:  25 February 2011

Yunji L. Corcoran
Affiliation:
Department of Materials Science, State University of New York at Stony Brook, Stony Brook, NY 11794–2275.
Alexander H. King
Affiliation:
Department of Materials Science, State University of New York at Stony Brook, Stony Brook, NY 11794–2275.
Nimal deLanerolle
Affiliation:
Standard Microsystem Co. Hauppauge, NY 11788.
Bonggi Kim
Affiliation:
Standard Microsystem Co. Hauppauge, NY 11788.
John Berg
Affiliation:
Standard Microsystem Co. Hauppauge, NY 11788.
Get access

Abstract

Titanium films of 0.5 µm thickness were sputter deposited on silicon substrates. After rapid thermal annealing at temperatures ranging from 600°C to 850°C for times up to 45 seconds in nitrogen, transmission electron microscope (TEM) cross section specimens were made from the wafers. Grain sizes of the resulting titanium disilicide were measured from TEM cross section micrographs. The results show that C49-TiSi2 has a different grain growth rate than C54-TiSi2- Under our experimental conditions, C54-TiSi2 has a much higher growth rate. Titanium silicide on arsenic implanted silicon substrates shows a lower grain growth rate than that on unimplanted substrates under the same conditions. The thickness of the silicide layer was also measured for each specimen. The relationship of thickness and grain size will be discussed.

Type
Research Article
Copyright
Copyright © Materials Research Society 1991

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Yakowitz, H. and Newbury, D. E., Scanning Electron Microscopy, Proceedings of the 9th Annual SEM Symposium, (1076) p. 151.Google Scholar
2. Bravman, J. and Sinclair, R. J., Electron Microsc. Tech., 1, 53 (1984).Google Scholar
3. Thompson, C. V. and Smith, H. I., Appl. Phys. Lett., 44, 603 (1984).Google Scholar
4. Mullins, W. W., Acta Metall., 6, 414 (1958).Google Scholar
5. Hillert, M., Acta Metall., 13, 227 (1965).Google Scholar
6. Corcoran, Y. L., King, A.H., deLanerolle, N., Kim, B., J. Elect. Mat. to be published.(1990)Google Scholar
7. Peterson, N. L., Inter.Met. Rev. 28, 65 (1983).Google Scholar
8. Pico, C. A. and Lagally, M. G., J. Appl. Phys. 64, 4957 (1988).Google Scholar