Hostname: page-component-586b7cd67f-t8hqh Total loading time: 0 Render date: 2024-11-25T15:46:25.487Z Has data issue: false hasContentIssue false
  • English
  • Français

Giant Electrostrictive Response in Poly(vinylidene-fluoride hexafluoropropylene) copolymer

Published online by Cambridge University Press:  10 February 2011

Xiaoyan Lu ,
Adriana Schirokauer  and
Jerry Scheinbeim
Xiaoyan Lu
Affiliation:
Dept. of Chemical and Biochemical Engineering, Rutgers University, Piscataway, NJ 08855
Adriana Schirokauer
Affiliation:
Dept. of Chemical and Biochemical Engineering, Rutgers University, Piscataway, NJ 08855
Jerry Scheinbeim
Affiliation:
Dept. of Chemical and Biochemical Engineering, Rutgers University, Piscataway, NJ 08855
Get access

Abstract

In the present study, the strain response of a new class of copolymers of PVF2 is investigated. Electrostrictive strains were measured in poly(vinylidene-fluoride hexafluoropropylene), P(VF2-HFP), using a capacitance method (air-gap capacitor), as a function of electric field. Three different thermal treatments (ice water quenched, air quenched and slow cooled) were given to samples of composition 5% and 15% HFP. Strains greater than 4 % were observed in the 5% HFP ice water quenched P(VF2-HFP) copolymer. Values of elastic modulus were lower for the quenched 5 % films than for the slow cooled ones, and in both cases they were higher than previously studied polyurethane elastomers and poly(vinylidene-fluoride trifluoroethylene) copolymers. Key words: Electrostrictive Polymer, Poly(vinylidene-fluoride hexafluoropropylene) copolymer, Ferroelectic, X-ray, DSC.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 600: Symposium FF – Electroactive Polymers , 1999 , 61
Copyright
Copyright © Materials Research Society 2000

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

[1] Ma, Z, Scheinbeim, J., Lee, J., and Newman, B.. High Field Electrostrictive Response of Polymers, Journal of Polymer Science: Part B: Polymer Physics, 32, 2721 (1994).Google Scholar
[2] Zhang, Q. M, Bharti, V., and Zhao, X.. Giant Electrostriction and Relaxor Ferroelectric Behavior in Electron-Irradiated Poly(vinylidene fluoride-trifluoroethylene) Copolymer, Science, 280, 2101 (1998).Google Scholar
[3] Newman, B. A., and Scheinbeim, J.. Polarization Mechanism in phase II Poly(vinylidene fluoride) films, Macromolecules, 16, 60 (1983).Google Scholar