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The Geochemistry of the Castile Brines: Implications for their Origin and Impact on the Wipp Site(1)
Published online by Cambridge University Press: 25 February 2011
Abstract
Pressurized brine reservoirs have been found in the Castile anhydrite which underlies the proposed Waste Isolation Pilot Plant. The major and minor component chemistry of the brines and the isotopic abundances of the brines and coexisting minerals have been determined and evaluated. Thermodynamic calculations indicate that the brines approach saturation with all major minerals in their host horizon. The brines therefore, appear to be in equilibrium with their geologic environment and do not have the capacity for substantially degrading the integrity of the site. When analyzed through solute versus bromide plots, the data indicate that the most likely origin for the brines is Permian seawater. As a result, the reservoirs appear to have been derived from waters no longer being introduced into the rock (i.e., they have a finite source).
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