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Formation, Patterning, and Polymerization of Surface Adlayers Using Self-Assembled Monolayers as Templates

Published online by Cambridge University Press:  15 February 2011

David W. Mosley ,
Mark A. Sellmyer  and
Joseph Jacobson
David W. Mosley
Affiliation:
Center for Bits and Atoms, MIT Media Laboratory 20 Ames St, Cambridge, MA 02139
Mark A. Sellmyer
Affiliation:
Center for Bits and Atoms, MIT Media Laboratory 20 Ames St, Cambridge, MA 02139
Joseph Jacobson
Affiliation:
Center for Bits and Atoms, MIT Media Laboratory 20 Ames St, Cambridge, MA 02139
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Abstract

Ordered surface adlayers of diacetylene-containing molecules were formed using amide hydrogen-bonding interactions with a pre-formed self-assembled monolayer on gold. Photopolymerization of the diacetylene molecules in the adlayer results in enhanced solvent and processing stability of the adlayer. Patterning of the base monolayer using soft lithography techniques allows patterning of the adlayer as well, and may lead to methods for templating soluble two-dimensional monolayer sheets.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 776: Symposium Q – Unconventional Approaches to Nanostructures with Applications in Electronics, Photonics, Information Storage and Sensing , 2003 , Q10.1
Copyright
Copyright © Materials Research Society 2003

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