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The Formation of Striped Phases by Charge Localization in Vanadium Phosphates

Published online by Cambridge University Press:  18 March 2011

Ranko P. Bontchev ,
Junghwan Do  and
Allan J. Jacobson
Ranko P. Bontchev
Affiliation:
Department of Chemistry, University of Houston, Houston, TX 77204-5641, USA
Junghwan Do
Affiliation:
Department of Chemistry, University of Houston, Houston, TX 77204-5641, USA
Allan J. Jacobson
Affiliation:
Department of Chemistry, University of Houston, Houston, TX 77204-5641, USA
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Abstract

The compound (H3O)1.5{[VO(H2O)]PO4}3·2.5H2O is a new member of a series of vanadium phosphates containing vanadium in both plus four and five oxidation states. Charge ordering occurs in these mixed vanadium phosphate layered compounds forming striped phases with different periodicities. The VOPO4 layers undulate as a consequence of differences in the O-O atom distances in the ordered V(V)O6 and V(IV)O6 octahedra.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 658: Symposium GG – Solid-State Chemistry of Inorganic Materials III , 2000 , GG1.7
Copyright
Copyright © Materials Research Society 2001

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