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Fabrication of ZnO Coated ZnS:Mn2+ Nanoparticles

Published online by Cambridge University Press:  26 February 2011

Shinji Ishizaki
Affiliation:
Laboratory for Material Science and Technology, Waseda University, 2–8–26, Nishiwaseda, Shinjuku-ku, Tokyo, 169–0051, Japan
Yusuke Kusakari
Affiliation:
Laboratory for Material Science and Technology, Waseda University, 2–8–26, Nishiwaseda, Shinjuku-ku, Tokyo, 169–0051, Japan
Masakazu Kobayashi
Affiliation:
Laboratory for Material Science and Technology, Waseda University, 2–8–26, Nishiwaseda, Shinjuku-ku, Tokyo, 169–0051, Japan
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Abstract

The fabrication of ZnO coated ZnS:Mn2+ nanoparticles were achieved using simple methods. ZnS:Mn2+ nanoparticles were prepared by a mechanical milling method. Coating of ZnO was then performed using a simple chemical method. Structural properties were evaluated by the X-ray powder diffraction (XRD) and the transmission electron microscope (TEM). Optical properties of the ZnO coated ZnS:Mn2+ nanoparticle were characterized by exciting the particle included solvent using an UV-LED (400 nm). Bright orange color fluorescence was observed, and the fluorescence intensity of ZnO coated ZnS:Mn2+ nanoparticles was enhanced as compared to uncoated ZnS:Mn2+ nanoparticles. The capping of the core surface has probably terminated surface defects of ZnS:Mn2+ nanoparticles, and resulted in the improved fluorescence intensity.

Type
Research Article
Copyright
Copyright © Materials Research Society 2005

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References

REFERENCES

1. Hao, E., Zhou, Z., Liu, J., Yang, B., Shen, J., Chem. Mater. 11, 11, 3096 (1991).Google Scholar
2. Malik, M. A., O'Brien, P., Revaprasadu, N., Chem. Mater. 14, 5, 2004 (2002).Google Scholar
3. Darugar, Q., Landes, C., Link, S., Schill, A., El-Sayed, M. A., Chem. Phys. Lett. 373, 3/4, 284 (2003).Google Scholar
4. Reiss, P., Bleuse, J., Pron, A., Nano Lett., 2, 7, 781 (2002).Google Scholar
5. Chen, W., Sammynaiken, R., Huang, Y., J. Appl. Phys. 88, 9, 5188 (2000).Google Scholar
6. Cao, L., Zhang, J., Ren, S. and Huang, S., Appl. Phys. Lett. 80, 23, 4300 (2002)Google Scholar
7. Ethiraj, A. S., Hebalkar, N., Kulkarni, S. K., Pasricha, R., Urban, J., Dem, C., Schmitt, M., Kiefer, W., Weinhardt, L., Joshi, S., Fink, R., Kumpf, C. and Umbach, E., J. Chem. Phys., 118, 19, 89458953 (2003).Google Scholar
8. Uchida, Y., Koizumi, T. and Matsui, K., Chem. Soc. Jap. 8, 535 (2000).Google Scholar
9. Bhargava, R. N., Gallagher, D., Hong, X. and Nurmikko, A., Phys. Rev. Lett. 72, 416 (1994).Google Scholar
10. Igarashi, T., Isobe, T., and Senna, M., Phys. Rev. B 56, 11, 6444 (1997).Google Scholar
11. Lu, S. W., Lee, B.I., Wang, Z. L., Tong, W., Wagner, B. K., Park, W. and Summers, C. J., J. Lumin. 92, 7982 (2001).Google Scholar
12. Gan, L. M., Liu, B., Chew, C. H., Chua, S. J., Loy, G. L., Xu, G. Q., Langmuir 13, 24, 6427 (1997).Google Scholar
13. Choi, H. H., Ollinger, M. and Singh, R. K., Appl. Phys. Lett. 82, 15, 2494 (2003).Google Scholar