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Fabrication and Morphological Investigation of Multi-walled Electrospun Polymeric Nanofibers

Published online by Cambridge University Press:  07 April 2014

Jamal Seyyed Monfared Zanjani
Affiliation:
Faculty of Engineering and Natural Sciences, Sabanci University, Tuzla, Istanbul 34956, Turkey
Burcu Saner Okan
Affiliation:
Sabanci University Nanotechnology Research and Application Center, SUNUM, Tuzla, Istanbul 34956, Turkey
Mehmet Yildiz
Affiliation:
Faculty of Engineering and Natural Sciences, Sabanci University, Tuzla, Istanbul 34956, Turkey
Yusuf Menceloglu
Affiliation:
Faculty of Engineering and Natural Sciences, Sabanci University, Tuzla, Istanbul 34956, Turkey
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Abstract

Multi-walled nanofibers with their outstanding properties have found expanding applications on drug delivery systems, biosensors, self-healing materials and many other state-of-the-art technologies. This work investigates the fabrication and morphological control of multi-walled structured electrospun polymeric nanofibers by multi-axial electrospinning system. This process is based on a nozzle allowing multi-axial extrusion of different fluids with concentric orders. Two spinnable polymers of poly(methyl methacrylate) and polyacrylamide are chosen for the fabrication of middle and outer walls of co-axial hollow nanofibers, respectively. Hansen’s solubility parameters are used to systematically optimize the solvent selection for each layer and control the degree of miscibility of layers with the purpose of tailoring the final wall morphology of nanofibers. Characterization studies are performed by Scanning Electron Microscopy, Energy-Dispersive X-ray Spectroscopy, Fourier Transform Infrared Spectroscopy, and Thermal Gravimetric Analyzer.

Type
Articles
Copyright
Copyright © Materials Research Society 2014 

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References

REFERENCES

Ozden-Yenigun, E., Simsek, E., Menceloglu, Y. Z., and Atilgan, C.Molecular basis for solvent dependent morphologies observed on electrosprayed surfaces,” Physical Chemistry Chemical Physics, vol. 15, pp. 1786217872, 2013.CrossRefGoogle ScholarPubMed
Demir, M. M., Gulgun, M. A., Menceloglu, Y. Z., Erman, B., Abramchuk, S. S., Makhaeva, E. E., Khokhlov, A. R., Matveeva, V. G., and Sulman, M. G.Palladium Nanoparticles by Electrospinning from Poly(acrylonitrile-co-acrylic acid)−PdCl2 Solutions. Relations between Preparation Conditions, Particle Size, and Catalytic Activity,” Macromolecules, vol. 37, pp. 17871792, 2004.CrossRefGoogle Scholar
Chan, K. H. K. and Kotaki, M., “Fabrication and morphology control of poly(methyl methacrylate) hollow structures via coaxial electrospinningJournal of Applied Polymer Science, vol. 111, pp. 408416, 2009.CrossRefGoogle Scholar
Kalra, V., Lee, J. H., Park, J. H., Marquez, M., and Joo, Y. L.Confined Assembly of Asymmetric Block-Copolymer Nanofibers via Multiaxial Jet Electrospinning,” Small, vol. 5, pp. 23232332, 2009.CrossRefGoogle ScholarPubMed
Chen, H., Wang, N., Di, J., Zhao, Y., Song, Y., and Jiang, L.Nanowire-in-Microtube Structured Core/Shell Fibers via Multifluidic Coaxial ElectrospinningLangmuir, vol. 26, pp. 1129111296, 2010.CrossRefGoogle ScholarPubMed
Liu, W., Ni, C., Chase, D. B., and Rabolt, J. F.Preparation of Multilayer Biodegradable Nanofibers by Triaxial ElectrospinningACS Macro Letters, vol. 2, pp. 466468, 2013.CrossRefGoogle Scholar
Han, D. and Steckl, A. J.Triaxial Electrospun Nanofiber Membranes for Controlled Dual Release of Functional Molecules,” ACS Applied Materials & Interfaces, vol. 5, pp. 82418245, 2013.CrossRefGoogle ScholarPubMed
Kurban, Z., Lovell, A., Bennington, S. M., Jenkins, D. W. K., Ryan, K. R., Jones, M. O., Skipper, N. T., and David, W. I. F.A Solution Selection Model for Coaxial Electrospinning and Its Application to Nanostructured Hydrogen Storage Materials,” The Journal of Physical Chemistry C, vol. 114, pp. 2120121213, 2010.CrossRefGoogle Scholar
Hansen, C. M., Hansen Solubility Parameters: A User's Handbook, Second Edition Boca Raton, FL: CRC Press, 2007.CrossRefGoogle Scholar
Kaniappan, K. and Latha, S.Certain Investigations on the Formulation and Characterization of Polystyrene / Poly(methyl methacrylate) Blends,” International Journal of ChemTech Research, vol. 3, pp. 708717, 2011.Google Scholar
Murugan, R., Mohan, S., and Bigotto, A.FTIR and Polarised Raman Spectra of Acrylamide and PolyacrylamideJournal of the Korean Physical Society, vol. 32, pp. 505512, 1998.Google Scholar
Kashiwagi, T., Inaba, A., Brown, J. E., Hatada, K., Kitayama, T., and Masuda, E.Effects of weak linkages on the thermal and oxidative degradation of poly(methyl methacrylates),” Macromolecules, vol. 19, pp. 21602168, 1986.CrossRefGoogle Scholar
Ferriol, M., Gentilhomme, A., Cochez, M., Oget, N., and Mieloszynski, J. L.Thermal degradation of poly(methyl methacrylate) (PMMA): modelling of DTG and TG curves,” Polymer Degradation and Stability, vol. 79, pp. 271281, 2003.CrossRefGoogle Scholar
Saeidi, A., Katbab, A. A., Vasheghani-Farahani, E., and Afshar, F.Formulation design, optimization, characterization and swelling behaviour of a cationic superabsorbent based on a copolymer of [3-(methacryloylamino)propyl]trimethylammonium chloride and acrylamide,” Polymer International, vol. 53, pp. 92100, 2004.CrossRefGoogle Scholar