Hostname: page-component-78c5997874-fbnjt Total loading time: 0 Render date: 2024-11-20T00:40:58.929Z Has data issue: false hasContentIssue false
  • English
  • Français

Extension of Multichannel Spectroscopic Ellipsometry into the Ultraviolet for Real Time Characterization of the Growth of Wide Bandgap Materials from 1.5 to 6.5 eV

Published online by Cambridge University Press:  10 February 2011

J. A. Zapien ,
R. W. Collins  and
R. Messier
J. A. Zapien
Affiliation:
Materials Research Laboratory and the Department of Engineering Science and Mechanics, The Pennsylvania State University, University Park, PA 16802.
R. W. Collins
Affiliation:
Materials Research Laboratory, the Department of Physics, and the Center for Thin Film Devices, The Pennsylvania State University, University Park, PA 16802.
R. Messier
Affiliation:
Materials Research Laboratory and the Department of Engineering Science and Mechanics, The Pennsylvania State University, University Park, PA 16802.
Get access

Abstract

In this article, we report the results of a successful effort to extend rotating-polarizer multichannel ellipsometry into the ultraviolet (uv) spectral region above 5 eV. Key modifications over previous system designs include (i) incorporation of a see-through deuterium (D2) lamp that allows a tandem Xe/D2 source configuration for a usable spectral output from 1.5 to 6.5 eV, (ii) MgF 2 Rochon polarizers for high transmission in the uv without the need for optical activity corrections, and (iii) a spectrograph with a concave grating blazed at 2500 A and internally mounted order-sorting filters. With these modifications, we can collect 132-point ellipsometric spectra over the range from 1.5 to 6.5 eV with a minimum acquisition time of 24.5 ms (one optical cycle). For averages over two and eighty optical cycles (requiring 49 ms and 1.96 s, respectively), the standard deviations in (Ψ, Δ) are (0.04°, 0.08°) and (0.008°, 0.015°), respectively, measured on a thermally-oxidized silicon wafer at a photon energy of 6 eV. In this first report, we briefly describe problems faced in the development of the new instrument. As an example of the applications of the instrument, we present the results of a real time study of the growth of a hexagonal boron nitride (BN) thin film by rf magnetron sputtering on a Si wafer substrate at a temperature of 250°C. The instrument is expected to be useful in BN film growth studies since the additional data in the uv assist in discriminating the wide band gap (Eg) hexagonal (4 < Eg < 5.8 eV) and cubic (Eg > 6 eV) phases of this material.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 569: Symposium U – In Situ Process Diagnostics and Modelling , 1999 , 71
Copyright
Copyright © Materials Research Society 1999

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

[1] See for example, several articles in: Collins, R. W., Aspnes, D. E., and Irene, E. A., Proc. 2nd International Conference on Spectroscopic Ellipsometry, (Elsevier, Amsterdam, 1998).Google Scholar
[2] An, I. and Collins, R. W., Rev. Sci. Instrum. 62, 1904 (1991).10.1063/1.1142390Google Scholar
[3] Hunderi, O. and Ryberg, R., Surf. Sci. 56, 182 (1976).10.1016/0039-6028(76)90445-3Google Scholar
[4] Aspnes, D. E. and Studna, A. A., Phys. Rev. B 27, 985 (1983).10.1103/PhysRevB.27.985Google Scholar
[5] Philipp, H. R., in Handbook of Optical Properties of Solids, edited by Palik, E. D., (Academic, New York, 1985), p. 719.Google Scholar
[6] Maltison, I. H., J. Opt. Soc. Am. 55, 1205 (1996).10.1364/JOSA.55.001205Google Scholar
[7] Otaño-Rivera, W., Pilione, L. J., Zapien, J. A., and Messier, R., J. Vac. Sci. Technol. A 16, 1331 (1998).10.1116/1.581146Google Scholar
[8] Cong, Y., An, I., Vedam, K., and Collins, R. W., Appl. Opt. 21, 2692 (1991).10.1364/AO.30.002692Google Scholar
[9] Kester, D. J., Ailey, K. S., and Davis, R. F., Diamond and Related Materials 3, 332 (1994).10.1016/0925-9635(94)90181-3Google Scholar
[10] See, for example, Plass, M. F., Fukarek, W., Kolitsh, A., Schell, N., and Möller, W., Thin Solid Films 305, 172 (1997).10.1016/S0040-6090(96)09575-2Google Scholar
[11] Jellison, G. E. Jr., and Modine, F. A., Appl. Phys. Lett. 69, 371 (1996); 69, 2137 (1996).10.1063/1.118064Google Scholar
[12] Stenzel, O., Hahn, J., Röder, M., Ehrlich, A., Prause, S., and Richter, F.. Phys. Stat. Sol. (a) 158, 281 (1996).Google Scholar