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Exploratory Studies of New NLO and Piezoelectric Polymers

Published online by Cambridge University Press:  21 February 2011

H. K. Hall Jr. ,
Anne B. Padias ,
Francesco Fuso ,
Zhende NI ,
Michael A. Mitchell  and
Thomas M. Leslie
H. K. Hall Jr.
Affiliation:
Carl S. Marvel Laboratories, Chemistry Department, University of Arizona, Tucson, AZ 85721
Anne B. Padias
Affiliation:
Carl S. Marvel Laboratories, Chemistry Department, University of Arizona, Tucson, AZ 85721
Francesco Fuso
Affiliation:
Carl S. Marvel Laboratories, Chemistry Department, University of Arizona, Tucson, AZ 85721
Zhende NI
Affiliation:
Carl S. Marvel Laboratories, Chemistry Department, University of Arizona, Tucson, AZ 85721
Michael A. Mitchell
Affiliation:
Carl S. Marvel Laboratories, Chemistry Department, University of Arizona, Tucson, AZ 85721
Thomas M. Leslie
Affiliation:
Hoechst-Celanese Co., 86 Morris Avenue, Summit, NJ 07901
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Abstract

Synthetic efforts toward novel NLO and piezoelectric polymers are described. NLO-phores are incorporated in the main chain of a polymer with all the dipoles in the same direction by polycondensation of AB-monomers. The polymers containing p-alkoxy-α-cyanocinnamate units in the backbone show cooperative enhancement of SHG in solution. For comparison, p-thio-α-cyanocinnamate is incorporated in the main chain and in the side chain of polymers. Novel potentially piezoelectric polymers synthesized include polymers containing multicyanocyclobutyl or -cyclopropyl groups and acrylonitrile copolymers.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 175: Symposium S – Multifunctional Materials , 1989 , 51
Copyright
Copyright © Materials Research Society 1990

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