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Experimental Evidence For Sulfur Induced Loss Of Ductility In Copper Shaped-Charge Jets

Published online by Cambridge University Press:  15 February 2011

D. K. Chan
Affiliation:
Lawrence Livermore National Laboratory, P.O. Box 808, Livermore, CA 94551
D. H. Lassila
Affiliation:
Lawrence Livermore National Laboratory, P.O. Box 808, Livermore, CA 94551
W. E. King
Affiliation:
Lawrence Livermore National Laboratory, P.O. Box 808, Livermore, CA 94551
E. L. Baker
Affiliation:
U. S. Army, ARDEC, Picatinny, NJ 07806
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Abstract

We have observed that a change in the bulk sulfur content of oxygen-free electronic copper markedly affects its high temperature (400–1000°C), high strain-rate (> 103 s−1) deformation and fracture behavior. These conditions are typical of those found in "jets" formed from the explosive deformation of copper shaped-charge liners. Specifically, an increase in the bulk sulfur concentration from 4 ppm to 8 ppm shortens the breakup time, tb, of the copper jets by nearly 20% as measured using flash x-ray radiographs recorded during breakup of the jets. At bulk concentrations of 4 ppm, the jet was observed to be uniform and axisymmetric with a breakup time of 186 µs. Jet particles exhibited length-to-diameter ratios of roughly 8:1. The addition of sulfur transformed the jet breakup behavior to non-uniform, non-axisymmetric rupture and reduced the breakup time to 147 µs. The length-to-diameter ratios decreased to roughly 5:1 in the sulfurdoped samples. Previously measured sulfur solubilities and diffusivities in copper at the temperatures where this material was processed indicates nearly all of the sulfur was localized to grain boundaries. Therefore, we infer that the increase in sulfur content at grain boundaries is directly responsible for the change in breakup performance of the shaped-charge jets.

Type
Research Article
Copyright
Copyright © Materials Research Society 1996

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References

1. Lichtenberger, A., in Proceedings of the 11 th International Symposium on Ballistics, Brussels, Belgium (1989), pp. 511.Google Scholar
2. Lassila, D. H., in Proceedings of the 13th International Symposium on Ballistics, Stockholm, Sweden (1992), pp. 549557; D. H. Lassila in Shock-Wave and High-Strain-Rate Phenomena in Materials, edited by M. A. Meyers, L. E. Murr, and K. P. Staudhammer (Marcel Dekker, New York, 1972), pp 543–554.Google Scholar
3. Duffy, M. L. and Golaski, S. T., U.S. Army Ballistic Research Laboratory Tech. Report No. BRL-TR-2800, 1987.Google Scholar
4. Prepared by Kuebrich, F. W., Northwest Industries, Albany, OR.Google Scholar
5. Interstitial impurities were measured by Luvak Inc., and metallic impurities were measured by Northern Analytical Laboratory Inc. using glow discharge mass spectrometry.Google Scholar
6. Kubaschewski, O., Alcock, C. B., and Spencer, P. J., Materials Thermochemistry, 6th ed. (Pergamon Press Inc., New York, 1993), pp. 127.Google Scholar
7. Fueki, K. and Ouchi, Y., Bull. Chem. Soc. Jap. 51, 2234 (1978).Google Scholar
8. Moya-Gontier, G. E. and Moya, F., Scripta Metall. 8, 153 (1974); G. E. Moya-Gontier and F. Moya, Scripta Metall. 9, 307 (1975).Google Scholar
9. 1995 Annual Book of ASTM Standards, edited by Furcola, N. C. et al. (ASTM 2.01, Philadelphia, PA, 1995) pp. 821, 837.Google Scholar