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Published online by Cambridge University Press: 25 February 2011
Striking increases in the intensity of donor-related, photoluminescence transitions are observed in undoped (1014-1015 cm-3) GaAs for excitation energies (Ee) in the vicinity of the band-gap energy (Eg). The enhancement has maxima at Ee consistent with excitation of the n=2 and 3 states of the free exciton (Xn=2,3) and appears to be correlated to the concentration of ionized donors, suggesting that the effects are related to capture of electron-hole pairs by ionized donors through trapping of Xn=2,3. The enhancement decreases monotonically as Ee increases to values as much as 12 meV above Eg.