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EPR Characterization of Carbon Coated Fiber

Published online by Cambridge University Press:  21 February 2011

Daryl Inniss*
Affiliation:
AT&T Bell Laboratories, 600 Mountain Avenue, Murray Hill, N.J. 07974
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Abstract

An amorphous carbon coating has been developed to improve the resistance of silica optical fibers to static fatigue and hydrogen permeation. The carbon coated optical fibers are characterized by electron paramagnetic resonance spectroscopy. A Lorentzian lineshape is observed, centered at the g value of 2.002. Intensity measurements as a function of temperature suggest that localized spin centers contribute to the spin resonance. It is shown that atmospheric control of the carbonaceous environment results in the removal of these EPR active sites.

Type
Research Article
Copyright
Copyright © Materials Research Society 1990

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References

1. Huff, R.G., DiMarcello, F. V., Hart, A. C. Jr., ”Amorphous Carbon Hermetically Coated Optical Fibers,” Proc. OFC, paper TUG, New Orleans (1988).Google Scholar
2. Wagoner, G., Bull. Am. Phy. Soc. 6, 129 (1961). 102Google Scholar
3. Dyson, F. J., Phys. Rev. 98, 349 (1955).Google Scholar
4. Mrozowski, S., Carbon 3, 305 (1965).CrossRefGoogle Scholar
5. Mrozowski, S., Carbon 20, 303 (1982).CrossRefGoogle Scholar
6. a)Hanafusa, H., Hibino, Y., and Yamamoto, F., J. Appl. Phys. 58 (3), 1356 (1985), b)Y. Watanabe, H. Kawazoe, K. Shibuya, Japanese Journal of Applied Physics 25 (3), 425 (1986), and c)Y. Hibino, and H. Hanafusa, Japanese Journal of Applied Physics 22 (12), L766 (1983), for example.Google Scholar
7. All intensity measurements were normalized to one. The relationship used to relate the integrated power absorbed (in this case the intensity, I) is usually assumed to be a Curie-Weiss Law expression of the form I 1/T.Google Scholar
8. Mrozowski, S., Carbon 17, 227 (1979).Google Scholar
9. a)Antonowicz, K., Proc. 5th Carbon Conference, Vol.1, p. 46, Pergamon Press, New York (1962). b)K. Antonowicz,, Proc. 5th Carbon Conference, Vol.1, p. 56, Pergamon Press, New York (1962)Google Scholar
10. Gutsze, A., Carbon 15, 343 (1977).Google Scholar